151
Hull JF, Himeda Y, Wang W-H, Hashiguchi B, Periana R, Szalda DJ, Fujita E (2012) Reversible
hydrogen storage using CO 2 and a proton-switchable iridium catalyst in aqueous media under
mild temperatures and pressures. Nature Chem 4:383. https://doi.org/10.1038/nchem.1295
Huš M, Dasireddy VDBC, Stefancic NS, Likozar B (2017a) Mechanism, kinetics and thermodynamics of carbon dioxide hydrogenation to methanol on Cu/ZnAl2O 4 spinel-type heterogeneous catalysts. Appl Catal B Env 207:267–278. https://doi.org/10.1016/j.apcatb.2017.01.077
Huš M, Drejc K, Neja SS, Damjan LJ, Venkata DBCD, Blaz L (2017b) Unravelling the mechanisms
of CO 2 hydrogenation to methanol on cu-based catalysts using first-principles ultiscale modelling and experiments. Cat Sci Technol 7:5900–5913. https://doi.org/10.1039/C7CY01659J
Ishitani O, Inoue C, Suzuki Y, Ibusuki T (1993) Photocatalytic reduction of carbon dioxide to
methane and acetic acid by an aqueous suspension of metal-deposited TiO 2 . J Photochem
Photobiol A Chem 72:269–271. https://doi.org/10.1016/1010-6030(93)80023-3
Jadhav SG, Prakash DV, Bhalchandra MB, Jyeshtharaj BJ (2014) Catalytic carbon dioxide hydrogenation to methanol: a review of recent studies. Chem Eng Res Design 92(11):2557–2567.
https://doi.org/10.1016/j.cherd.2014.03.005
Jeong H, Cho CH, Kim TH (2012) Effect of Zr and pH in the preparation of Cu/ZnO catalysts for
the methanol synthesis by CO 2 hydrogenation. Reac Kinet Mech Cat 106(2):435–443. https://
doi.org/10.1007/s11144-012-0441-5
Jeong Y, Kim I, Kang JY, Yan N, Jeong H, Park JK, Park JH, Jung JC (2016) Effect of the aging
time of the precipitate on the activity of Cu/ZnO catalysts for alcohol-assisted low temperature methanol synthesis. J Mol Cat A Chem 418–419:168–174. https://doi.org/10.1016/j.
molcata.2016.03.044
Joo OS, Jung KD (2003) Stability of ZnAl 2 O 4 catalyst for reverse-water-gas-shift reaction
(RWGSR), bull. Korean Chem Soc 24:86–90. https://doi.org/10.5012/bkcs.2003.24.1.086
Joo OS, Jung KD, Moon I, Rozovskii AY, Lin GI, Han SH, Uhm SJ (1999) Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE process). Ind
Eng Chem Res 38:1808–1812. https://doi.org/10.1021/ie9806848
Joo OS, Jung KD, Jung Y (2004) CAMERE process for methanol synthesis from CO 2 hydrogenation. Stud Surf Sci Catal 153:67–72. https://doi.org/10.1016/S0167-2991(04)80221-0
Kar S, Kothandaraman J, Goeppert A, Prakash GKS (2018) Advances in catalytic homogeneous
hydrogenation of carbon dioxide to methanol. J CO2 Util 23:212–218. https://doi.org/10.1016/j.
jcou.2017.10.023
Kattel S, Binhang Y, Jingguang CG, Ping L (2016) CO 2 hydrogenation on Pt, Pt/SiO 2 and Pt/
TiO 2 : importance of synergy between Pt and oxide support. J Catal 343:115–126. https://doi.
org/10.1016/j.jcat.2015.12.019
Kauw M, Benders RMJ, Visser C (2015) Green methanol from hydrogen and carbon dioxide using
geothermal energy and/or hydropower in Iceland or excess renewable electricity in Germany.
Energy 90:208–217. https://doi.org/10.1016/j.energy.2015.06.002
Kieffer R, Ramaroson E, Deluzarche A, Trambouze Y (1981) A comparison of reactivity in the
synthesis of methanol from CO 2 +H 2 and CO+H 2 (catalysts Cu, Zn/Al 2 O 3 , P=515×104 Pa).
React Kinet Catal Lett 16:207–212. https://doi.org/10.1007/BF02065459
Kim L, Liao WC, Tada S, Lam E, Verel R, Bansode A, Urakawa A, Comas-Vives A, Copéret C
(2017) Carbon dioxide hydrogenation on zirconia-supported copper nanoparticles: reaction
intermediates and the role of the metal – support interface. Angew Chem Int Ed 56:2318–2323.
https://doi.org/10.1002/anie.201610166
Kim J, Jeong C, Baik JH, Suh YW (2018) Phases of Cu/Zn/Al/Zr precursors linked to the property
and activity of their final catalysts in CO 2 hydrogenation to methanol. Catal Today in press.
https://doi.org/10.1016/j.cattod.2018.09.008
Kiss AA, Pragt JJ, Vos HJ, Bargeman G, de Groot MT (2016) Novel efficient process for methanol synthesis by CO 2 hydrogenation. Chem Eng J 284:260–269. https://doi.org/10.1016/j.
cej.2015.08.101
5 Selective Hydrogenation of Carbon Dioxide into Methanol
Hull JF, Himeda Y, Wang W-H, Hashiguchi B, Periana R, Szalda DJ, Fujita E (2012) Reversible
hydrogen storage using CO 2 and a proton-switchable iridium catalyst in aqueous media under
mild temperatures and pressures. Nature Chem 4:383. https://doi.org/10.1038/nchem.1295
Huš M, Dasireddy VDBC, Stefancic NS, Likozar B (2017a) Mechanism, kinetics and thermodynamics of carbon dioxide hydrogenation to methanol on Cu/ZnAl2O 4 spinel-type heterogeneous catalysts. Appl Catal B Env 207:267–278. https://doi.org/10.1016/j.apcatb.2017.01.077
Huš M, Drejc K, Neja SS, Damjan LJ, Venkata DBCD, Blaz L (2017b) Unravelling the mechanisms
of CO 2 hydrogenation to methanol on cu-based catalysts using first-principles ultiscale modelling and experiments. Cat Sci Technol 7:5900–5913. https://doi.org/10.1039/C7CY01659J
Ishitani O, Inoue C, Suzuki Y, Ibusuki T (1993) Photocatalytic reduction of carbon dioxide to
methane and acetic acid by an aqueous suspension of metal-deposited TiO 2 . J Photochem
Photobiol A Chem 72:269–271. https://doi.org/10.1016/1010-6030(93)80023-3
Jadhav SG, Prakash DV, Bhalchandra MB, Jyeshtharaj BJ (2014) Catalytic carbon dioxide hydrogenation to methanol: a review of recent studies. Chem Eng Res Design 92(11):2557–2567.
https://doi.org/10.1016/j.cherd.2014.03.005
Jeong H, Cho CH, Kim TH (2012) Effect of Zr and pH in the preparation of Cu/ZnO catalysts for
the methanol synthesis by CO 2 hydrogenation. Reac Kinet Mech Cat 106(2):435–443. https://
doi.org/10.1007/s11144-012-0441-5
Jeong Y, Kim I, Kang JY, Yan N, Jeong H, Park JK, Park JH, Jung JC (2016) Effect of the aging
time of the precipitate on the activity of Cu/ZnO catalysts for alcohol-assisted low temperature methanol synthesis. J Mol Cat A Chem 418–419:168–174. https://doi.org/10.1016/j.
molcata.2016.03.044
Joo OS, Jung KD (2003) Stability of ZnAl 2 O 4 catalyst for reverse-water-gas-shift reaction
(RWGSR), bull. Korean Chem Soc 24:86–90. https://doi.org/10.5012/bkcs.2003.24.1.086
Joo OS, Jung KD, Moon I, Rozovskii AY, Lin GI, Han SH, Uhm SJ (1999) Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE process). Ind
Eng Chem Res 38:1808–1812. https://doi.org/10.1021/ie9806848
Joo OS, Jung KD, Jung Y (2004) CAMERE process for methanol synthesis from CO 2 hydrogenation. Stud Surf Sci Catal 153:67–72. https://doi.org/10.1016/S0167-2991(04)80221-0
Kar S, Kothandaraman J, Goeppert A, Prakash GKS (2018) Advances in catalytic homogeneous
hydrogenation of carbon dioxide to methanol. J CO2 Util 23:212–218. https://doi.org/10.1016/j.
jcou.2017.10.023
Kattel S, Binhang Y, Jingguang CG, Ping L (2016) CO 2 hydrogenation on Pt, Pt/SiO 2 and Pt/
TiO 2 : importance of synergy between Pt and oxide support. J Catal 343:115–126. https://doi.
org/10.1016/j.jcat.2015.12.019
Kauw M, Benders RMJ, Visser C (2015) Green methanol from hydrogen and carbon dioxide using
geothermal energy and/or hydropower in Iceland or excess renewable electricity in Germany.
Energy 90:208–217. https://doi.org/10.1016/j.energy.2015.06.002
Kieffer R, Ramaroson E, Deluzarche A, Trambouze Y (1981) A comparison of reactivity in the
synthesis of methanol from CO 2 +H 2 and CO+H 2 (catalysts Cu, Zn/Al 2 O 3 , P=515×104 Pa).
React Kinet Catal Lett 16:207–212. https://doi.org/10.1007/BF02065459
Kim L, Liao WC, Tada S, Lam E, Verel R, Bansode A, Urakawa A, Comas-Vives A, Copéret C
(2017) Carbon dioxide hydrogenation on zirconia-supported copper nanoparticles: reaction
intermediates and the role of the metal – support interface. Angew Chem Int Ed 56:2318–2323.
https://doi.org/10.1002/anie.201610166
Kim J, Jeong C, Baik JH, Suh YW (2018) Phases of Cu/Zn/Al/Zr precursors linked to the property
and activity of their final catalysts in CO 2 hydrogenation to methanol. Catal Today in press.
https://doi.org/10.1016/j.cattod.2018.09.008
Kiss AA, Pragt JJ, Vos HJ, Bargeman G, de Groot MT (2016) Novel efficient process for methanol synthesis by CO 2 hydrogenation. Chem Eng J 284:260–269. https://doi.org/10.1016/j.
cej.2015.08.101
5 Selective Hydrogenation of Carbon Dioxide into Methanol