148
Angelo L, Girleanu M, Ersen O, Serra C, Parkhomenko K, Roger AC (2016) Catalyst synthesis by continuous coprecipitation under micro-fluidic conditions: application to the preparation of catalysts for methanol synthesis from CO 2 /H 2 . Catal Today 270:59–67. https://doi.
org/10.1016/j.cattod.2015.09.028
Arena F, Barbera K, Italiano G, Bonura G, Spadaro L, Frusteri F (2007) Synthesis, characterization and activity pattern of Cu–ZnO/ZrO 2 catalysts in the hydrogenation of carbon dioxide to
methanol. J Catal 249(2):185–194. https://doi.org/10.1016/j.jcat.2007.04.003
Arena F, Italiano G, Barbera K, Bonura G, Spadaro L, Frusteri F (2009) Basic evidences for
methanol-synthesis catalyst design. Catal Today 143(1–2):80–85. https://doi.org/10.1016/j.
cattod.2008.11.022
Ashley AE, Thompson AL, O'Hare D (2009) Non-metal-mediated homogeneous hydrogenation of CO 2 to CH 3 OH. Angew Chem Int Ed 48(52):9839–9843. https://doi.org/10.1002/
anie.200905466
Aurian-Blajeni B, Halmann M, Manassen J (1983) Electrochemical measurement on the photoelectrochemical reduction of aqueous carbon dioxide on p-gallium phosphide and
p-gallium arsenide semiconductor electrodes. Solar Ener Mat 8(4):425–440. https://doi.
org/10.1016/0165-1633(83)90007-2
Balaraman E, Ben-David Y, Milstein D (2011a) Unprecedented catalytic hydrogenation of urea
derivatives to amines and methanol. Angew Chem Int Ed 50(49):11702–11705. https://doi.
org/10.1002/anie.201106612
Balaraman E, Gunanathan C, Zhang J, Shimon LJ, Milstein D (2011b) Efficient hydrogenation of
organic carbonates, carbamates and formates indicates alternative routes to methanol based on
CO 2 and CO. Nat Chem 3(8):609–614. https://doi.org/10.1038/nchem.1089
Baltes C, Vikojevic S, Schuth F (2008) Correlations between synthesis, precursor, and catalyst
structure and activity of a large set of CuO/ZnO/Al 2 O 3 catalysts for methanol synthesis. J Catal
258(2):334–344. https://doi.org/10.1016/j.jcat.2008.07.004
Barton Cole E, Lakkaraju PS, Rampulla DM, Morris AJ, Abelev E, Bocarsly AB (2010) Using
a one-electron shuttle for the multielectron reduction of CO 2 to methanol: kinetic, mechanistic, and structural insights. J Am Chem Soc 132(33):11539–11551. https://doi.org/10.1021/
ja1023496
Barton EE, Rampulla DM, Bocarsly AB (2008) Selective solar-driven reduction of CO 2 to methanol using a catalyzed p-GaP based Photoelectrochemical cell. J Am Chem Soc 130(20):6342–
6344. https://doi.org/10.1021/ja0776327
Behrens M, Brennecke D, Girgsdies F, Kißner S, Trunschke A, Nasrudin N, Zakaria S, Idris NF,
Hamid SBA, Kniep B, Fischer R, Busser W, Muhler M, Schlögl R (2011) Understanding the
complexity of a catalyst synthesis: co-precipitation of mixed Cu, Zn, Al hydroxycarbonate
precursors for Cu/ZnO/Al 2 O 3 catalysts investigated by titration experiments. Appl Catal A Gen
392(1–2):93–102. https://doi.org/10.1016/j.apcata.2010.10.031
Behrens M, Studt F, Kasatkin I, Kühl S, Hävecker M, Abild-Pedersen F, Zander S, Girgsdies F,
Kurr P, Kniep BL, Tovar M, Fischer RW, Nørskov JK, Schlögl R (2012) The active site of
methanol synthesis over Cu/ZnO/Al 2 O 3 industrial catalysts. Science 759:893–898. https://doi.
org/10.1126/science.1219831
Bellotti D, Rivarolo M, Magistri L, Massardo AF (2017) Feasibility study of methanol production plant from hydrogen and captured carbon dioxide. J CO2 Utiliz 21:132–138. https://doi.
org/10.1016/j.jcou.2017.07.001
Bonura G, Cordaro C, Cannilla C, Arena F, Frusteri F (2014) The changing nature of the active
site of Cu-Zn-Zr catalysts for the CO 2 hydrogenation reaction to methanol. Appl Catal B Env
152–153:152–161. https://doi.org/10.1016/j.apcatb.2014.01.035
Boomer EH, Morris HE (1932) The hydrogen-carbon dioxide reaction. J Am Chem Soc 54(1):407–
407. https://doi.org/10.1021/ja01340a509
Boston DJ, Xu C, Armstrong DW, MacDonnell F (2013) Photochemical reduction of carbon dioxide to methanol and formate in a homogeneous system with pyridinium catalysts. J Am Chem
Soc 135(44):16252–16255. https://doi.org/10.1021/ja406074w
D. P. Minh et al.
Angelo L, Girleanu M, Ersen O, Serra C, Parkhomenko K, Roger AC (2016) Catalyst synthesis by continuous coprecipitation under micro-fluidic conditions: application to the preparation of catalysts for methanol synthesis from CO 2 /H 2 . Catal Today 270:59–67. https://doi.
org/10.1016/j.cattod.2015.09.028
Arena F, Barbera K, Italiano G, Bonura G, Spadaro L, Frusteri F (2007) Synthesis, characterization and activity pattern of Cu–ZnO/ZrO 2 catalysts in the hydrogenation of carbon dioxide to
methanol. J Catal 249(2):185–194. https://doi.org/10.1016/j.jcat.2007.04.003
Arena F, Italiano G, Barbera K, Bonura G, Spadaro L, Frusteri F (2009) Basic evidences for
methanol-synthesis catalyst design. Catal Today 143(1–2):80–85. https://doi.org/10.1016/j.
cattod.2008.11.022
Ashley AE, Thompson AL, O'Hare D (2009) Non-metal-mediated homogeneous hydrogenation of CO 2 to CH 3 OH. Angew Chem Int Ed 48(52):9839–9843. https://doi.org/10.1002/
anie.200905466
Aurian-Blajeni B, Halmann M, Manassen J (1983) Electrochemical measurement on the photoelectrochemical reduction of aqueous carbon dioxide on p-gallium phosphide and
p-gallium arsenide semiconductor electrodes. Solar Ener Mat 8(4):425–440. https://doi.
org/10.1016/0165-1633(83)90007-2
Balaraman E, Ben-David Y, Milstein D (2011a) Unprecedented catalytic hydrogenation of urea
derivatives to amines and methanol. Angew Chem Int Ed 50(49):11702–11705. https://doi.
org/10.1002/anie.201106612
Balaraman E, Gunanathan C, Zhang J, Shimon LJ, Milstein D (2011b) Efficient hydrogenation of
organic carbonates, carbamates and formates indicates alternative routes to methanol based on
CO 2 and CO. Nat Chem 3(8):609–614. https://doi.org/10.1038/nchem.1089
Baltes C, Vikojevic S, Schuth F (2008) Correlations between synthesis, precursor, and catalyst
structure and activity of a large set of CuO/ZnO/Al 2 O 3 catalysts for methanol synthesis. J Catal
258(2):334–344. https://doi.org/10.1016/j.jcat.2008.07.004
Barton Cole E, Lakkaraju PS, Rampulla DM, Morris AJ, Abelev E, Bocarsly AB (2010) Using
a one-electron shuttle for the multielectron reduction of CO 2 to methanol: kinetic, mechanistic, and structural insights. J Am Chem Soc 132(33):11539–11551. https://doi.org/10.1021/
ja1023496
Barton EE, Rampulla DM, Bocarsly AB (2008) Selective solar-driven reduction of CO 2 to methanol using a catalyzed p-GaP based Photoelectrochemical cell. J Am Chem Soc 130(20):6342–
6344. https://doi.org/10.1021/ja0776327
Behrens M, Brennecke D, Girgsdies F, Kißner S, Trunschke A, Nasrudin N, Zakaria S, Idris NF,
Hamid SBA, Kniep B, Fischer R, Busser W, Muhler M, Schlögl R (2011) Understanding the
complexity of a catalyst synthesis: co-precipitation of mixed Cu, Zn, Al hydroxycarbonate
precursors for Cu/ZnO/Al 2 O 3 catalysts investigated by titration experiments. Appl Catal A Gen
392(1–2):93–102. https://doi.org/10.1016/j.apcata.2010.10.031
Behrens M, Studt F, Kasatkin I, Kühl S, Hävecker M, Abild-Pedersen F, Zander S, Girgsdies F,
Kurr P, Kniep BL, Tovar M, Fischer RW, Nørskov JK, Schlögl R (2012) The active site of
methanol synthesis over Cu/ZnO/Al 2 O 3 industrial catalysts. Science 759:893–898. https://doi.
org/10.1126/science.1219831
Bellotti D, Rivarolo M, Magistri L, Massardo AF (2017) Feasibility study of methanol production plant from hydrogen and captured carbon dioxide. J CO2 Utiliz 21:132–138. https://doi.
org/10.1016/j.jcou.2017.07.001
Bonura G, Cordaro C, Cannilla C, Arena F, Frusteri F (2014) The changing nature of the active
site of Cu-Zn-Zr catalysts for the CO 2 hydrogenation reaction to methanol. Appl Catal B Env
152–153:152–161. https://doi.org/10.1016/j.apcatb.2014.01.035
Boomer EH, Morris HE (1932) The hydrogen-carbon dioxide reaction. J Am Chem Soc 54(1):407–
407. https://doi.org/10.1021/ja01340a509
Boston DJ, Xu C, Armstrong DW, MacDonnell F (2013) Photochemical reduction of carbon dioxide to methanol and formate in a homogeneous system with pyridinium catalysts. J Am Chem
Soc 135(44):16252–16255. https://doi.org/10.1021/ja406074w
D. P. Minh et al.