111
© Springer Nature Switzerland AG 2020
Inamuddin et al. (eds.), Conversion of Carbon Dioxide into Hydrocarbons Vol. 2
Technology, Environmental Chemistry for a Sustainable World 41,
https://doi.org/10.1007/978-3-030-28638-5_5
Chapter 5
Selective Hydrogenation of Carbon
Dioxide into Methanol
Doan Pham Minh, Anne-Cécile Roger, Ksenia Parkhomenko,
Valentin L’Hospital, Bruna Rego de Vasconcelos, Kyoung Ro,
Devinder Mahajan, Lyufei Chen, Sharanjit Singh, and Dai-Viet N. Vo
Contents
5.1 Introduction
113
5.2 Thermodynamic Equilibrium of Carbon Dioxide Hydrogenation
115
5.3 Selective Hydrogenation of Carbon Dioxide to Methanol in the Gas Phase:
Heterogeneous Catalysis
118
5.3.1 Copper-Based Catalysts for Carbon Dioxide Hydrogenation
in the Gas Phase
119
5.3.2 Other Transition Metal-Based Catalysts for Carbon Dioxide Hydrogenation
in the Gas Phase
123
5.3.3 Noble Metal-Based Catalysts for Carbon Dioxide Hydrogenation
in the Gas Phase
124
D. Pham Minh (*)
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE,
Albi cedex 09, France
e-mail: doan.phamminh@mines-albi.fr
A.-C. Roger · K. Parkhomenko · V. L’Hospital
Université de Strasbourg, ICPEES groupe Energie et Carburants pour un Environnement
Durable, UMR 7515, Strasbourg Cedex 2, France
e-mail: annececile.roger@unistra.fr; parkhomenko@unistra.fr
B. Rego de Vasconcelos
Biomass Technology Laboratory, Department of Chemical Engineering, Université de
Sherbrooke, Sherbrooke, QC, Canada
e-mail: bruna.rego.de.vasconcelos@usherbrooke.ca
K. Ro
USDA-ARS, Coastal Plains Soil, Water & Plant Research Center, Florence, SC, USA
e-mail: Kyoung.Ro@usda.gov
D. Mahajan
Institute of Gas Innovation and Technology, Advanced Energy Research and Technology and
Materials Science and Chemical Engineering Department, Stony Brook University,
Stony Brook, NY, USA
e-mail: devinder.mahajan@stonybrook.edu
© Springer Nature Switzerland AG 2020
Inamuddin et al. (eds.), Conversion of Carbon Dioxide into Hydrocarbons Vol. 2
Technology, Environmental Chemistry for a Sustainable World 41,
https://doi.org/10.1007/978-3-030-28638-5_5
Chapter 5
Selective Hydrogenation of Carbon
Dioxide into Methanol
Doan Pham Minh, Anne-Cécile Roger, Ksenia Parkhomenko,
Valentin L’Hospital, Bruna Rego de Vasconcelos, Kyoung Ro,
Devinder Mahajan, Lyufei Chen, Sharanjit Singh, and Dai-Viet N. Vo
Contents
5.1 Introduction
113
5.2 Thermodynamic Equilibrium of Carbon Dioxide Hydrogenation
115
5.3 Selective Hydrogenation of Carbon Dioxide to Methanol in the Gas Phase:
Heterogeneous Catalysis
118
5.3.1 Copper-Based Catalysts for Carbon Dioxide Hydrogenation
in the Gas Phase
119
5.3.2 Other Transition Metal-Based Catalysts for Carbon Dioxide Hydrogenation
in the Gas Phase
123
5.3.3 Noble Metal-Based Catalysts for Carbon Dioxide Hydrogenation
in the Gas Phase
124
D. Pham Minh (*)
Université de Toulouse, IMT Mines Albi, UMR CNRS 5302, Centre RAPSODEE,
Albi cedex 09, France
e-mail: doan.phamminh@mines-albi.fr
A.-C. Roger · K. Parkhomenko · V. L’Hospital
Université de Strasbourg, ICPEES groupe Energie et Carburants pour un Environnement
Durable, UMR 7515, Strasbourg Cedex 2, France
e-mail: annececile.roger@unistra.fr; parkhomenko@unistra.fr
B. Rego de Vasconcelos
Biomass Technology Laboratory, Department of Chemical Engineering, Université de
Sherbrooke, Sherbrooke, QC, Canada
e-mail: bruna.rego.de.vasconcelos@usherbrooke.ca
K. Ro
USDA-ARS, Coastal Plains Soil, Water & Plant Research Center, Florence, SC, USA
e-mail: Kyoung.Ro@usda.gov
D. Mahajan
Institute of Gas Innovation and Technology, Advanced Energy Research and Technology and
Materials Science and Chemical Engineering Department, Stony Brook University,
Stony Brook, NY, USA
e-mail: devinder.mahajan@stonybrook.edu