Manceau A, Tommaseo C, Rihs S, Geoffroy N, Chateigner D, Schlegel M, Tisserand D, Marcus
MA, Tamura N, Chen Z-S (2005) Natural speciation of Mn, Ni, and Zn at the micrometer scale
in a clayey paddy soil using X-ray fluorescence, absorption, and diffraction. Geochim
Cosmochim Acta 69(16):4007–4034
Manceau A, Kersten M, Marcus MA, Geoffroy N, Granina L (2007a) Ba and Ni speciation in a
nodule of binary Mn oxide phase composition from Lake Baikal. Geochim Cosmochim Acta 71
(8):1967–1981
Manceau A, Lanson M, Geoffroy N (2007b) Natural speciation of Ni, Zn, Ba, and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction. Geochim
Cosmochim Acta 71(1):95–128
Manceau A, Marcus MA, Grangeon S, Lanson M, Lanson B, Gaillot AC, Skanthakumar S,
Soderholm L (2013) Short-range and long-range order of phyllomanganate nanoparticles
determined using high-energy X-ray scattering. J Appl Crystallogr 46(1):193–209
Manceau A, Lanson M, Takahashi Y (2014) Mineralogy and crystal chemistry of Mn, Fe, Co, Ni,
and Cu in a deep-sea Pacific polymetallic nodule. Am Mineral 99(10):2068–2083
Marafatto FF, Strader ML, Gonzalez-Holguera J, Schwartzberg A, Gilbert B, Peña J (2015) Rate
and mechanism of the photoreduction of birnessite (MnO2) nanosheets. Proc Natl Acad Sci 112
(15):4600–4605
Marcus MA, Manceau A, Kersten M (2004) Mn, Fe, Zn and As speciation in a fast-growing
ferromanganese marine nodule. Geochim Cosmochim Acta 68(14):3125–3136
Matocha CJ, Elzinga EJ, Sparks DL (2001) Reactivity of Pb(II) at the Mn(III,IV) (Oxyhydr)
oxideÀwater Interface. Environ Sci Technol 35(14):2967–2972
McCann CM, Gray ND, Tourney J, Davenport RJ, Wade M, Finlay N, Hudson-Edwards KA,
Johnson KL (2015) Remediation of a historically Pb contaminated soil using a model natural
Mn oxide waste. Chemosphere 138:211–217
McKenzie RM (1980) The adsorption of lead and other heavy metals on oxides of manganese and
iron. Aust J Soil Res 18:61–73
McKenzie RM (1989) Manganese oxides and hydroxides. In: Dixon JB, Weed SB (eds) Minerals in
soil environments. Soil Science Society of America, Madison, pp 439–461
Michalkova Z, Komarek M, Sillerova H, Della Puppa L, Joussein E, Bordas F, Vanek A, Vanek O,
Ettler V (2014) Evaluating the potential of three Fe- and Mn-(nano)oxides for the stabilization of
Cd, Cu and Pb in contaminated soils. J Environ Manag 146:226–234
Miyata N, Tani Y, Iwahori K, Soma M (2004) Enzymatic formation of manganese oxides by an
Acremonium-like hyphomycete fungus, strain KR21-2. FEMS Microbiol Ecol 47(1):101–109
Miyata N, Maruo K, Tani Y, Tsuno H, Seyama H, Soma M, Iwahori K (2006) Production of
biogenic manganese oxides by anamorphic Ascomycete Fungi isolated from streambed pebbles.
Geomicrobiol J 23(2):63–73
Morgan JJ (2005) Kinetics of reaction between O 2 and Mn(II) species in aqueous solutions.
Geochim Cosmochim Acta 69(1):35–48
Neaman A, Mouélé F, Trolard F, Bourrié G (2004) Improved methods for selective dissolution of
Mn oxides: applications for studying trace element associations. Appl Geochem 19(6):973–979
Negra C, Ross DS, Lanzirotti A (2005a) Oxidizing behavior of soil manganese: interactions among
abundance, oxidation state, and pH. Soil Sci Soc Am J 69(1):87–95
Negra C, Ross DS, Lanzirotti A (2005b) Soil manganese oxides and trace metals: competitive
sorption and microfocused synchrotron X-ray fluorescence mapping. Soil Sci Soc Am J 69
(2):353–361
O’Reilly SE, Hochella MF Jr (2003) Lead sorption efficiencies of natural and synthetic Mn and
Fe-oxides. Geochim Cosmochim Acta 67(23):4471–4487
Ostwald J, Frazer FW (1973) Chemical and mineralogical investigations on deep sea manganese
nodules from the Southern Ocean. Mineral Deposita 8(4):303–311
Palumbo B, Bellanca A, Neri R, Roe MJ (2001) Trace metal partitioning in Fe-Mn nodules from
Sicilian soils, Italy. Chem Geol 173(4):257–269
426
S. Grangeon et al.
MA, Tamura N, Chen Z-S (2005) Natural speciation of Mn, Ni, and Zn at the micrometer scale
in a clayey paddy soil using X-ray fluorescence, absorption, and diffraction. Geochim
Cosmochim Acta 69(16):4007–4034
Manceau A, Kersten M, Marcus MA, Geoffroy N, Granina L (2007a) Ba and Ni speciation in a
nodule of binary Mn oxide phase composition from Lake Baikal. Geochim Cosmochim Acta 71
(8):1967–1981
Manceau A, Lanson M, Geoffroy N (2007b) Natural speciation of Ni, Zn, Ba, and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction. Geochim
Cosmochim Acta 71(1):95–128
Manceau A, Marcus MA, Grangeon S, Lanson M, Lanson B, Gaillot AC, Skanthakumar S,
Soderholm L (2013) Short-range and long-range order of phyllomanganate nanoparticles
determined using high-energy X-ray scattering. J Appl Crystallogr 46(1):193–209
Manceau A, Lanson M, Takahashi Y (2014) Mineralogy and crystal chemistry of Mn, Fe, Co, Ni,
and Cu in a deep-sea Pacific polymetallic nodule. Am Mineral 99(10):2068–2083
Marafatto FF, Strader ML, Gonzalez-Holguera J, Schwartzberg A, Gilbert B, Peña J (2015) Rate
and mechanism of the photoreduction of birnessite (MnO2) nanosheets. Proc Natl Acad Sci 112
(15):4600–4605
Marcus MA, Manceau A, Kersten M (2004) Mn, Fe, Zn and As speciation in a fast-growing
ferromanganese marine nodule. Geochim Cosmochim Acta 68(14):3125–3136
Matocha CJ, Elzinga EJ, Sparks DL (2001) Reactivity of Pb(II) at the Mn(III,IV) (Oxyhydr)
oxideÀwater Interface. Environ Sci Technol 35(14):2967–2972
McCann CM, Gray ND, Tourney J, Davenport RJ, Wade M, Finlay N, Hudson-Edwards KA,
Johnson KL (2015) Remediation of a historically Pb contaminated soil using a model natural
Mn oxide waste. Chemosphere 138:211–217
McKenzie RM (1980) The adsorption of lead and other heavy metals on oxides of manganese and
iron. Aust J Soil Res 18:61–73
McKenzie RM (1989) Manganese oxides and hydroxides. In: Dixon JB, Weed SB (eds) Minerals in
soil environments. Soil Science Society of America, Madison, pp 439–461
Michalkova Z, Komarek M, Sillerova H, Della Puppa L, Joussein E, Bordas F, Vanek A, Vanek O,
Ettler V (2014) Evaluating the potential of three Fe- and Mn-(nano)oxides for the stabilization of
Cd, Cu and Pb in contaminated soils. J Environ Manag 146:226–234
Miyata N, Tani Y, Iwahori K, Soma M (2004) Enzymatic formation of manganese oxides by an
Acremonium-like hyphomycete fungus, strain KR21-2. FEMS Microbiol Ecol 47(1):101–109
Miyata N, Maruo K, Tani Y, Tsuno H, Seyama H, Soma M, Iwahori K (2006) Production of
biogenic manganese oxides by anamorphic Ascomycete Fungi isolated from streambed pebbles.
Geomicrobiol J 23(2):63–73
Morgan JJ (2005) Kinetics of reaction between O 2 and Mn(II) species in aqueous solutions.
Geochim Cosmochim Acta 69(1):35–48
Neaman A, Mouélé F, Trolard F, Bourrié G (2004) Improved methods for selective dissolution of
Mn oxides: applications for studying trace element associations. Appl Geochem 19(6):973–979
Negra C, Ross DS, Lanzirotti A (2005a) Oxidizing behavior of soil manganese: interactions among
abundance, oxidation state, and pH. Soil Sci Soc Am J 69(1):87–95
Negra C, Ross DS, Lanzirotti A (2005b) Soil manganese oxides and trace metals: competitive
sorption and microfocused synchrotron X-ray fluorescence mapping. Soil Sci Soc Am J 69
(2):353–361
O’Reilly SE, Hochella MF Jr (2003) Lead sorption efficiencies of natural and synthetic Mn and
Fe-oxides. Geochim Cosmochim Acta 67(23):4471–4487
Ostwald J, Frazer FW (1973) Chemical and mineralogical investigations on deep sea manganese
nodules from the Southern Ocean. Mineral Deposita 8(4):303–311
Palumbo B, Bellanca A, Neri R, Roe MJ (2001) Trace metal partitioning in Fe-Mn nodules from
Sicilian soils, Italy. Chem Geol 173(4):257–269
426
S. Grangeon et al.