Light-induced structural changes, 110
Limits of detection (LOD), 385
Linde type A zeolite (LTA)
Ag-LTA systems, 87
Pb clusters, 97–99
silver-exchanged zeolites, 83
Linde type L zeolite (LTL), 92
Linker molecules, 113
Liquid phase epitaxial growth (LPE), 127
Lower-energy triplet state, 331, 332
Luminescence
dynamics, 53, 54
host-guest composites (see Host-guest
composites)
microscopy images, 9
quenching, 27
Ru
2+ complex, 24
ZL single crystals, 19
Luminescent polymers, 229
Luminescent silver clusters in zeolites
activation, 83
optoelectronic properties, 86–87
parameters, 85
photophysical properties, 83–85
silver-exchanged zeolites, 82–83
space-confinement, 83
structure-to-properties relationship, 85–86
synthesis strategy, 82, 85, 86
Luminescent silver-zeolite composites
advanced matrix codes, 97
humidity sensors, 95–96
OLED, 96
optically encoded microcarriers, 96
optoelectronic devices, 96
phosphors, lighting applications, 94–95
ZEOLED, 97
Luminescent solar concentrators (LSC), 56
Luminescent stopcocks, 16
M
Magnetic properties, 107
Magnetic resonance imaging (MRI), 391
Magnetism
alkylcarboxylate intercalated layered Co
and Cu hydroxides, 292
anionic photochromic compound, 291
LDHs, 291–292
photoswitching, 291–292
Melting processes, 115
Memory devices, 107
Merocyanine (MC), 111, 136
Metal building block (MBB), 156–158, 160,
168, 174
Metal clusters
catalytic activity, 77
DNA-templated luminescent Ag
nanoclusters, 78–80
gold clusters, 77
molecule-like energy gaps, 77
photoluminescence, 77
selective synthesis, 78
small metal clusters, 77
stabilization protocols, 78
thiolates, 77
See also Silver clusters
Metal organic frameworks (MOFs)
applications, 157
bathochromic shift, 168
catalytic sites, 157
crystal structure, 168
decay parameters, 170
emission decays, 169
emission lifetimes, 169
energy level diagram, 170
extrinsic introduction, 113–114
functional porous materials, 156, 157
geometry, 156
Huang-Rhys parameters, 168
intrinsic introduction, 113–114
with lanthanides ions, 82
photoactive guests, 158–160
photophysical properties, 167
RuBpy
crystallization inclusion technique, 161
direct synthetic methods, 166
emission decays, 164, 165
Huang-Rhys factors, 163
isostructural HKUST-1(Zn) MOF, 161
molecules, 166
parameters, 164, 165
photophysical properties, 161
physical properties, 162
RuBpy@HKUST-1(Zn), 164
RuBpy@HUKUST-1(Zn), 166
RuBpy@USF2, 164
state decay pathways, 164
steady-state emission spectra, 161–163
USF2, 161
water and alcohols, 166
RWLC-3
biexponential function, 172
bnb network, 171
cavity environment, 174
Index
401
Limits of detection (LOD), 385
Linde type A zeolite (LTA)
Ag-LTA systems, 87
Pb clusters, 97–99
silver-exchanged zeolites, 83
Linde type L zeolite (LTL), 92
Linker molecules, 113
Liquid phase epitaxial growth (LPE), 127
Lower-energy triplet state, 331, 332
Luminescence
dynamics, 53, 54
host-guest composites (see Host-guest
composites)
microscopy images, 9
quenching, 27
Ru
2+ complex, 24
ZL single crystals, 19
Luminescent polymers, 229
Luminescent silver clusters in zeolites
activation, 83
optoelectronic properties, 86–87
parameters, 85
photophysical properties, 83–85
silver-exchanged zeolites, 82–83
space-confinement, 83
structure-to-properties relationship, 85–86
synthesis strategy, 82, 85, 86
Luminescent silver-zeolite composites
advanced matrix codes, 97
humidity sensors, 95–96
OLED, 96
optically encoded microcarriers, 96
optoelectronic devices, 96
phosphors, lighting applications, 94–95
ZEOLED, 97
Luminescent solar concentrators (LSC), 56
Luminescent stopcocks, 16
M
Magnetic properties, 107
Magnetic resonance imaging (MRI), 391
Magnetism
alkylcarboxylate intercalated layered Co
and Cu hydroxides, 292
anionic photochromic compound, 291
LDHs, 291–292
photoswitching, 291–292
Melting processes, 115
Memory devices, 107
Merocyanine (MC), 111, 136
Metal building block (MBB), 156–158, 160,
168, 174
Metal clusters
catalytic activity, 77
DNA-templated luminescent Ag
nanoclusters, 78–80
gold clusters, 77
molecule-like energy gaps, 77
photoluminescence, 77
selective synthesis, 78
small metal clusters, 77
stabilization protocols, 78
thiolates, 77
See also Silver clusters
Metal organic frameworks (MOFs)
applications, 157
bathochromic shift, 168
catalytic sites, 157
crystal structure, 168
decay parameters, 170
emission decays, 169
emission lifetimes, 169
energy level diagram, 170
extrinsic introduction, 113–114
functional porous materials, 156, 157
geometry, 156
Huang-Rhys parameters, 168
intrinsic introduction, 113–114
with lanthanides ions, 82
photoactive guests, 158–160
photophysical properties, 167
RuBpy
crystallization inclusion technique, 161
direct synthetic methods, 166
emission decays, 164, 165
Huang-Rhys factors, 163
isostructural HKUST-1(Zn) MOF, 161
molecules, 166
parameters, 164, 165
photophysical properties, 161
physical properties, 162
RuBpy@HKUST-1(Zn), 164
RuBpy@HUKUST-1(Zn), 166
RuBpy@USF2, 164
state decay pathways, 164
steady-state emission spectra, 161–163
USF2, 161
water and alcohols, 166
RWLC-3
biexponential function, 172
bnb network, 171
cavity environment, 174
Index
401