432. Enomoto M, Kojima N (2005) Charge transfer phase transition and ferromagnetism in a novel
iron mixed-valence complex (n-C 3 H 7 )4N[Fe
II
Fe
III
(tto) 3 ] (tto¼C 2 OS 3 ). Synth Met
152:457–460. https://doi.org/10.1016/j.synthmet.2005.07.177
433. Kida N, Hikita M, Kashima I, Enomoto M, Itoi M, Kojima N (2009) Mössbauer spectroscopic
study of photo-sensitive organic-inorganic hybrid system, (SP)[Fe(II)Fe(III)(dto) 3 ](dto ¼
C 2 O 2 S 2 , SP ¼ spiropyran). Polyhedron 28:1694–1697. https://doi.org/10.1016/j.poly.2008.
10.060
434. Kida N, Hikita M, Kashima I, Okubo M, Itoi M, Enomoto M, Kato K, Takata M, Kojima N
(2009) Control of charge transfer phase transition and ferromagnetism by photoisomerization
of spiropyran for an organic-inorganic hybrid system, (SP)[FeIIFeIlI(dto) 3 ] (SP ¼ spiropyran,
dto ¼ C 2 O 2 S 2 ). J Am Chem Soc 131:212–220. https://doi.org/10.1021/ja806879a
435. Tanaka N, Okazawa A, Sugahara A, Kojima N (2015) Development of a photoresponsive
organic-inorganic hybrid magnet: layered cobalt hydroxides intercalated with spiropyran
anions. Bull Chem Soc Jpn 88:1150–1155. https://doi.org/10.1246/bcsj.20150129
436. Abellán G, Coronado E, Martí-Gastaldo C, Ribera A, Jordá JL, García H (2014) Photoswitching in a hybrid material made of magnetic layered double hydroxides intercalated
with azobenzene molecules. Adv Mater 26:4156–4162. https://doi.org/10.1002/adma.
201400713
437. Abellán G, Jordá JL, Atienzar P, Varela M, Jaafar M, Gómez-Herrero J, Zamora F, Ribera A,
García H, Coronado E (2015) Stimuli-responsive hybrid materials: breathing in magnetic
layered double hydroxides induced by a thermoresponsive molecule. Chem Sci 6:1949–1958.
https://doi.org/10.1039/C4SC03460K
438. Okubo M, Enomoto M, Kojima N (2005) Study on photomagnetism of 2-D magnetic
compounds coupled with photochromic diarylethene cations. Synth Met 152:461–464.
https://doi.org/10.1016/j.synthmet.2005.07.181
439. Shimizu H, Okubo M, Nakamoto A, Enomoto M, Kojima N (2006) Enhancement of the curie
temperature by isomerization of diarylethene (DAE) for an organic-inorganic hybrid system:
Co 4 (OH) 7 (DAE) 0.5 Á3H 2 O. Inorg Chem 45:10240–10247. https://doi.org/10.1021/ic061498u
440. Kojima N, Okubo M, Shimizu H, Enomoto M (2007) Control of magnetism by isomerization
of intercalated molecules in organic-inorganic hybrid systems. Coord Chem Rev
251:2665–2673. https://doi.org/10.1016/j.ccr.2007.08.025
441. Abellán G, Coronado E, Martí-Gastaldo C, Waerenborgh J, Ribera A (2013) Interplay between
chemical composition and Cation ordering in the magnetism of Ni/Fe layered double hydroxides. Inorg Chem 52:10147–10157. https://doi.org/10.1021/ic401576q
442. Kojima N, Aoki W, Itoi M, Ono Y, Seto M, Kobayashi Y, Maeda Y (2001) Charge transfer
phase transition and ferromagnetism in a mixed-valence iron complex, (n-C 3 H 7 )4N
[Fe
II
Fe
III (dto) 3 ] (dto ¼ C 2 O 2 S 2 ). Solid State Commun 120:165–170. https://doi.org/10.1016/
S0038-1098(01)00366-0
443. Ono Y, Okubo M, Kojima N (2003) Crystal structure and ferromagnetism of (n-C 3 H 7 )4N
[Co
II Fe
III (dto) 3 ] (dto ¼ C 2 O 2 S 2 ). Solid State Commun 126:291–296. https://doi.org/10.1016/
S0038-1098(02)00825-6
444. Carrasco JA, Abellán G, Coronado E (2018) Influence of morphology in the magnetic
properties of layered double hydroxides. J Mater Chem C 6:1187–1198. https://doi.org/10.
1039/c7tc05569b
445. Hornick C, Rabu P, Drillon M (2000) Hybrid organic-inorganic multilayer materials: influence
of π electrons as magnetic media in a series of bridged-layer compounds M 2 (OH) 4-x A x/2 (M ¼
cu(II) or co(II), a ¼ dicarboxylate anion). Polyhedron 19:259–266. https://doi.org/10.1016/
S0277-5387(99)00355-1
446. Matsuda K, Irie M (2000) Photoswitching of intramolecular magnetic interaction: a
diarylethene photochromic spin coupler. Chem Lett 29:16–17. https://doi.org/10.1246/cl.
2000.16
Photofunctions of Dye-Clay Hybrids: Recent Developments
319
iron mixed-valence complex (n-C 3 H 7 )4N[Fe
II
Fe
III
(tto) 3 ] (tto¼C 2 OS 3 ). Synth Met
152:457–460. https://doi.org/10.1016/j.synthmet.2005.07.177
433. Kida N, Hikita M, Kashima I, Enomoto M, Itoi M, Kojima N (2009) Mössbauer spectroscopic
study of photo-sensitive organic-inorganic hybrid system, (SP)[Fe(II)Fe(III)(dto) 3 ](dto ¼
C 2 O 2 S 2 , SP ¼ spiropyran). Polyhedron 28:1694–1697. https://doi.org/10.1016/j.poly.2008.
10.060
434. Kida N, Hikita M, Kashima I, Okubo M, Itoi M, Enomoto M, Kato K, Takata M, Kojima N
(2009) Control of charge transfer phase transition and ferromagnetism by photoisomerization
of spiropyran for an organic-inorganic hybrid system, (SP)[FeIIFeIlI(dto) 3 ] (SP ¼ spiropyran,
dto ¼ C 2 O 2 S 2 ). J Am Chem Soc 131:212–220. https://doi.org/10.1021/ja806879a
435. Tanaka N, Okazawa A, Sugahara A, Kojima N (2015) Development of a photoresponsive
organic-inorganic hybrid magnet: layered cobalt hydroxides intercalated with spiropyran
anions. Bull Chem Soc Jpn 88:1150–1155. https://doi.org/10.1246/bcsj.20150129
436. Abellán G, Coronado E, Martí-Gastaldo C, Ribera A, Jordá JL, García H (2014) Photoswitching in a hybrid material made of magnetic layered double hydroxides intercalated
with azobenzene molecules. Adv Mater 26:4156–4162. https://doi.org/10.1002/adma.
201400713
437. Abellán G, Jordá JL, Atienzar P, Varela M, Jaafar M, Gómez-Herrero J, Zamora F, Ribera A,
García H, Coronado E (2015) Stimuli-responsive hybrid materials: breathing in magnetic
layered double hydroxides induced by a thermoresponsive molecule. Chem Sci 6:1949–1958.
https://doi.org/10.1039/C4SC03460K
438. Okubo M, Enomoto M, Kojima N (2005) Study on photomagnetism of 2-D magnetic
compounds coupled with photochromic diarylethene cations. Synth Met 152:461–464.
https://doi.org/10.1016/j.synthmet.2005.07.181
439. Shimizu H, Okubo M, Nakamoto A, Enomoto M, Kojima N (2006) Enhancement of the curie
temperature by isomerization of diarylethene (DAE) for an organic-inorganic hybrid system:
Co 4 (OH) 7 (DAE) 0.5 Á3H 2 O. Inorg Chem 45:10240–10247. https://doi.org/10.1021/ic061498u
440. Kojima N, Okubo M, Shimizu H, Enomoto M (2007) Control of magnetism by isomerization
of intercalated molecules in organic-inorganic hybrid systems. Coord Chem Rev
251:2665–2673. https://doi.org/10.1016/j.ccr.2007.08.025
441. Abellán G, Coronado E, Martí-Gastaldo C, Waerenborgh J, Ribera A (2013) Interplay between
chemical composition and Cation ordering in the magnetism of Ni/Fe layered double hydroxides. Inorg Chem 52:10147–10157. https://doi.org/10.1021/ic401576q
442. Kojima N, Aoki W, Itoi M, Ono Y, Seto M, Kobayashi Y, Maeda Y (2001) Charge transfer
phase transition and ferromagnetism in a mixed-valence iron complex, (n-C 3 H 7 )4N
[Fe
II
Fe
III (dto) 3 ] (dto ¼ C 2 O 2 S 2 ). Solid State Commun 120:165–170. https://doi.org/10.1016/
S0038-1098(01)00366-0
443. Ono Y, Okubo M, Kojima N (2003) Crystal structure and ferromagnetism of (n-C 3 H 7 )4N
[Co
II Fe
III (dto) 3 ] (dto ¼ C 2 O 2 S 2 ). Solid State Commun 126:291–296. https://doi.org/10.1016/
S0038-1098(02)00825-6
444. Carrasco JA, Abellán G, Coronado E (2018) Influence of morphology in the magnetic
properties of layered double hydroxides. J Mater Chem C 6:1187–1198. https://doi.org/10.
1039/c7tc05569b
445. Hornick C, Rabu P, Drillon M (2000) Hybrid organic-inorganic multilayer materials: influence
of π electrons as magnetic media in a series of bridged-layer compounds M 2 (OH) 4-x A x/2 (M ¼
cu(II) or co(II), a ¼ dicarboxylate anion). Polyhedron 19:259–266. https://doi.org/10.1016/
S0277-5387(99)00355-1
446. Matsuda K, Irie M (2000) Photoswitching of intramolecular magnetic interaction: a
diarylethene photochromic spin coupler. Chem Lett 29:16–17. https://doi.org/10.1246/cl.
2000.16
Photofunctions of Dye-Clay Hybrids: Recent Developments
319