258. Liu J, Zhang G (2014) Recent advances in synthesis and applications of clay-based
photocatalysts: a review. Phys Chem Chem Phys 16:8178–8192. https://doi.org/10.1039/
c3cp54146k
259. Kameyama H, Narumi F, Hattori T, Kameyama H (2006) Oxidation of cyclohexene with
molecular oxygen catalyzed by cobalt porphyrin complexes immobilized on montmorillonite.
J Mol Catal A Chem 258:172–177. https://doi.org/10.1016/j.molcata.2006.05.022
260. Tsukamoto T, Shimada T, Takagi S (2018) Artificial photosynthesis model: photochemical
reaction system with efficient light-harvesting function on inorganic nanosheets. ACS Omega
3:18563–18571. https://doi.org/10.1021/acsomega.8b02594
261. Remello SN, Kuttassery F, Mathew S, Thomas A, Yamamoto D, Nabetani Y, Sano K,
Tachibana H, Inoue H (2018) Two-electron oxidation of water to form hydrogen peroxide
catalysed by silicon-porphyrins. Sustain Energy Fuels 2:1966–1973. https://doi.org/10.1039/
c8se00102b
262. Tatsumi D, Tsukamoto T, Honna R, Hoshino S, Shimada T, Takagi S (2017) Highly selective
photochemical epoxidation of cyclohexene sensitized by Ru(II) porphyrinclay hybrid catalyst.
Chem Lett 46:1311–1314. https://doi.org/10.1246/cl.170521
263. Jain A, Achari A, Eswaramoorthy M, George SJ (2016) Light induced: in situ postmodification of clay-chromophore hybrids for multiple white light emissions. J Mater Chem
C 4:2748–2751. https://doi.org/10.1039/c5tc03319e
264. Ishida Y, Shimada T, Masui D, Tachibana H, Inoue H, Takagi S (2011) Efficient excited
energy transfer reaction in clay/porphyrin complex toward an artificial light-harvesting system.
J Am Chem Soc 133:14280–14286. https://doi.org/10.1021/ja204425u
265. Takagi S, Eguchi M, Shimada T, Hamatani S, Inoue H (2007) Energy transfer reaction of
cationic porphyrin complexes on the clay surface: effect of sample preparation method. Res
Chem Intermed 33:177–189. https://doi.org/10.1163/156856707779160889
266. Takagi S, Shimada T, Ishida Y, Fujimura T, Masui D, Tachibana H, Eguchi M, Inoue H (2013)
Size-matching effect on inorganic nanosheets: control of distance, alignment, and orientation
of molecular adsorption as a bottom-up methodology for nanomaterials. Langmuir
29:2108–2119. https://doi.org/10.1021/la3034808
267. Rao KV, Datta KKR, Eswaramoorthy M, George SJ (2013) Highly pure solid-state white-light
emission from solution-processable soft-hybrids. Adv Mater 25:1713–1718. https://doi.org/
10.1002/adma.201204407
268. Sato K, Matsubara K, Hagiwara S, Saito K, Yagi M, Takagi S, Yui T (2015) Remarkable
stimulation of emission quenching on a clay surface. Langmuir 31:27–31. https://doi.org/10.
1021/la504597t
269. Takagi S, Eguchi M, Tryk DA, Inoue H (2006) Porphyrin photochemistry in inorganic/organic
hybrid materials: clays, layered semiconductors, nanotubes, and mesoporous materials. J
Photochem Photobiol C: Photochem Rev 7:104–126. https://doi.org/10.1016/j.
jphotochemrev.2006.04.002
270. Nakato T, Iwata Y, Kuroda K, Kaneko M, Kato C (1993) Intercalation of a free-base porphyrin
into layered tetratitanic acid. J Chem Soc Dalt Trans:1405–1409. https://doi.org/10.1039/
DT9930001405
271. Sasai R, Kato Y, Soontornchaiyakul W, Usami H, Masumori A, Norimatsu W, Fujimura T,
Takagi S (2017) Photoinduced electron transfer in layer-by-layer thin solid films containing
cobalt oxide nanosheets, porphyrin, and methyl viologen. Phys Chem Chem Phys
19:5611–5616. https://doi.org/10.1039/c6cp07250j
272. Gu Z, Gao M, Lu L, Liu Y, Yang S (2015) Montmorillonite functionalized with zwitterionic
surfactant as a highly efficient adsorbent for herbicides. Ind Eng Chem Res 54:4947–4955.
https://doi.org/10.1021/acs.iecr.5b00438
273. Si Y, Zhou J, Chen H, Zhou D (2004) Photostabilization of the herbicide bensulfuron-methyl
by using organoclays. Chemosphere 54:943–950. https://doi.org/10.1016/j.chemosphere.
2003.09.033
Photofunctions of Dye-Clay Hybrids: Recent Developments
309
photocatalysts: a review. Phys Chem Chem Phys 16:8178–8192. https://doi.org/10.1039/
c3cp54146k
259. Kameyama H, Narumi F, Hattori T, Kameyama H (2006) Oxidation of cyclohexene with
molecular oxygen catalyzed by cobalt porphyrin complexes immobilized on montmorillonite.
J Mol Catal A Chem 258:172–177. https://doi.org/10.1016/j.molcata.2006.05.022
260. Tsukamoto T, Shimada T, Takagi S (2018) Artificial photosynthesis model: photochemical
reaction system with efficient light-harvesting function on inorganic nanosheets. ACS Omega
3:18563–18571. https://doi.org/10.1021/acsomega.8b02594
261. Remello SN, Kuttassery F, Mathew S, Thomas A, Yamamoto D, Nabetani Y, Sano K,
Tachibana H, Inoue H (2018) Two-electron oxidation of water to form hydrogen peroxide
catalysed by silicon-porphyrins. Sustain Energy Fuels 2:1966–1973. https://doi.org/10.1039/
c8se00102b
262. Tatsumi D, Tsukamoto T, Honna R, Hoshino S, Shimada T, Takagi S (2017) Highly selective
photochemical epoxidation of cyclohexene sensitized by Ru(II) porphyrinclay hybrid catalyst.
Chem Lett 46:1311–1314. https://doi.org/10.1246/cl.170521
263. Jain A, Achari A, Eswaramoorthy M, George SJ (2016) Light induced: in situ postmodification of clay-chromophore hybrids for multiple white light emissions. J Mater Chem
C 4:2748–2751. https://doi.org/10.1039/c5tc03319e
264. Ishida Y, Shimada T, Masui D, Tachibana H, Inoue H, Takagi S (2011) Efficient excited
energy transfer reaction in clay/porphyrin complex toward an artificial light-harvesting system.
J Am Chem Soc 133:14280–14286. https://doi.org/10.1021/ja204425u
265. Takagi S, Eguchi M, Shimada T, Hamatani S, Inoue H (2007) Energy transfer reaction of
cationic porphyrin complexes on the clay surface: effect of sample preparation method. Res
Chem Intermed 33:177–189. https://doi.org/10.1163/156856707779160889
266. Takagi S, Shimada T, Ishida Y, Fujimura T, Masui D, Tachibana H, Eguchi M, Inoue H (2013)
Size-matching effect on inorganic nanosheets: control of distance, alignment, and orientation
of molecular adsorption as a bottom-up methodology for nanomaterials. Langmuir
29:2108–2119. https://doi.org/10.1021/la3034808
267. Rao KV, Datta KKR, Eswaramoorthy M, George SJ (2013) Highly pure solid-state white-light
emission from solution-processable soft-hybrids. Adv Mater 25:1713–1718. https://doi.org/
10.1002/adma.201204407
268. Sato K, Matsubara K, Hagiwara S, Saito K, Yagi M, Takagi S, Yui T (2015) Remarkable
stimulation of emission quenching on a clay surface. Langmuir 31:27–31. https://doi.org/10.
1021/la504597t
269. Takagi S, Eguchi M, Tryk DA, Inoue H (2006) Porphyrin photochemistry in inorganic/organic
hybrid materials: clays, layered semiconductors, nanotubes, and mesoporous materials. J
Photochem Photobiol C: Photochem Rev 7:104–126. https://doi.org/10.1016/j.
jphotochemrev.2006.04.002
270. Nakato T, Iwata Y, Kuroda K, Kaneko M, Kato C (1993) Intercalation of a free-base porphyrin
into layered tetratitanic acid. J Chem Soc Dalt Trans:1405–1409. https://doi.org/10.1039/
DT9930001405
271. Sasai R, Kato Y, Soontornchaiyakul W, Usami H, Masumori A, Norimatsu W, Fujimura T,
Takagi S (2017) Photoinduced electron transfer in layer-by-layer thin solid films containing
cobalt oxide nanosheets, porphyrin, and methyl viologen. Phys Chem Chem Phys
19:5611–5616. https://doi.org/10.1039/c6cp07250j
272. Gu Z, Gao M, Lu L, Liu Y, Yang S (2015) Montmorillonite functionalized with zwitterionic
surfactant as a highly efficient adsorbent for herbicides. Ind Eng Chem Res 54:4947–4955.
https://doi.org/10.1021/acs.iecr.5b00438
273. Si Y, Zhou J, Chen H, Zhou D (2004) Photostabilization of the herbicide bensulfuron-methyl
by using organoclays. Chemosphere 54:943–950. https://doi.org/10.1016/j.chemosphere.
2003.09.033
Photofunctions of Dye-Clay Hybrids: Recent Developments
309