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density intercalation of porphyrin into transparent clay membrane without aggregation. Langmuir 29:5060–5065. https://doi.org/10.1021/la4003737
18. Konno S, Fujimura T, Otani Y, Shimada T, Inoue H, Takagi S (2014) Microstructures of the
porphyrin/viologen monolayer on the clay surface: segregation or integration? J Phys Chem C
118:20504–20510. https://doi.org/10.1021/jp5076274
19. Nakayama A, Mizuno J, Ohtani Y, Shimada T, Takagi S (2018) Elucidation of the adsorption
distribution of cationic porphyrin on the inorganic surface by energy transfer as a molecular
ruler. J Phys Chem C 122:4365–4371. https://doi.org/10.1021/acs.jpcc.7b12104
20. Sohmiya M, Nakamura T, Sugahara Y, Ogawa M (2018) Distribution control-oriented intercalation of a cationic metal complex into layered silicates modified with organosulfonic-acid
moieties. Langmuir 34:4762–4773. https://doi.org/10.1021/acs.langmuir.8b00547
21. Eguchi M, Takagi S, Inoue H (2006) The orientation control of dicationic porphyrins on clay
surfaces by solvent polarity. Chem Lett 35:14–15. https://doi.org/10.1246/cl.2006.14
22. Sasai R, Shichi T, Gekko K, Takagi K (2000) Continuously changing the conformational
dependence of saponite hybrid materials on the intercalation degree: electric linear dichroism
of stilbazolium derivatives intercalated in saponite clay. Bull Chem Soc Jpn 73:1925–1931.
https://doi.org/10.1246/bcsj.73.1925
23. Neumann MG, Gessner F, Schmitt CC, Sartori R (2002) Influence of the layer charge and clay
particle size on the interactions between the cationic dye methylene blue and clays in an
aqueous suspension. J Colloid Interface Sci 255:254–259. https://doi.org/10.1006/jcis.2002.
8654
24. Okada T, Ide Y, Ogawa M (2012) Organic-inorganic hybrids based on ultrathin oxide layers:
designed nanostructures for molecular recognition. Chem Asian J 7:1980–1992. https://doi.
org/10.1002/asia.201101015
25. Okada T, Seki Y, Ogawa M (2014) Designed nanostructures of clay for controlled adsorption
of organic compounds. J Nanosci Nanotechnol 14:2121–2134. https://doi.org/10.1166/jnn.
2014.8597
26. Ruiz-Hitzky E, Aranda P, Akkari M, Khaorapapong N, Ogawa M (2019) Photoactive
nanoarchitectures based on clays incorporating TiO 2 and ZnO nanoparticles. Beilstein J
Nanotechnol 10:1140–1156. https://doi.org/10.3762/bjnano.10.114
27. Deepracha S, Vibulyaseak K, Ogawa M (2019) Complexation of TiO 2 with clays and clay
minerals for hierarchically designed functional hybrids. In: Advanced supramolecular
nanoarchitectonics. Elsevier, Amsterdam, pp 125–150
28. Intasa-ard SG, Ogawa M (2018) Layered silicates as a possible drug carrier. In: Tamanoi F
(ed) Mesoporous silica-based Nanomaterials and biomedical applications, part B. Elsevier,
Amsterdam, pp 117–136
29. Ogawa M (1998) Organized molecular assemblies on the surfaces of inorganic solidsphotofunctional inorganic-organic supramolecular systems. Annu Rep Prog Chem Sect C
Phys Chem 94:209. https://doi.org/10.1039/pc094209
30. Lagaly G, Ogawa M, Dékány I (2006) Chapter 7.3 clay mineral organic interactions. Dev Clay
Sci 1:309–377
31. Shichi T, Takagi K (2000) Clay minerals as photochemical reaction fields. J Photochem
Photobiol C: Photochem Rev 1:113–130. https://doi.org/10.1016/S1389-5567(00)00008-3
32. Granquist WT, Pollack SS (1960) A study of the synthesis of hectorite. Pergamon Press,
Oxford
33. Ogawa M, Wada T, Kuroda K (1995) Intercalation of pyrene into alkylammonium-exchanged
swelling layered silicates: the effects of the arrangements of the interlayer alkylammonium
ions on the states of adsorbates. Langmuir 11:4598–4600. https://doi.org/10.1021/
la00011a068
296
T. Yamaguchi et al.
Res 21:275–280. https://doi.org/10.1021/ar00151a004
17. Fujimura T, Shimada T, Hamatani S, Onodera S, Sasai R, Inoue H, Takagi S (2013) High
density intercalation of porphyrin into transparent clay membrane without aggregation. Langmuir 29:5060–5065. https://doi.org/10.1021/la4003737
18. Konno S, Fujimura T, Otani Y, Shimada T, Inoue H, Takagi S (2014) Microstructures of the
porphyrin/viologen monolayer on the clay surface: segregation or integration? J Phys Chem C
118:20504–20510. https://doi.org/10.1021/jp5076274
19. Nakayama A, Mizuno J, Ohtani Y, Shimada T, Takagi S (2018) Elucidation of the adsorption
distribution of cationic porphyrin on the inorganic surface by energy transfer as a molecular
ruler. J Phys Chem C 122:4365–4371. https://doi.org/10.1021/acs.jpcc.7b12104
20. Sohmiya M, Nakamura T, Sugahara Y, Ogawa M (2018) Distribution control-oriented intercalation of a cationic metal complex into layered silicates modified with organosulfonic-acid
moieties. Langmuir 34:4762–4773. https://doi.org/10.1021/acs.langmuir.8b00547
21. Eguchi M, Takagi S, Inoue H (2006) The orientation control of dicationic porphyrins on clay
surfaces by solvent polarity. Chem Lett 35:14–15. https://doi.org/10.1246/cl.2006.14
22. Sasai R, Shichi T, Gekko K, Takagi K (2000) Continuously changing the conformational
dependence of saponite hybrid materials on the intercalation degree: electric linear dichroism
of stilbazolium derivatives intercalated in saponite clay. Bull Chem Soc Jpn 73:1925–1931.
https://doi.org/10.1246/bcsj.73.1925
23. Neumann MG, Gessner F, Schmitt CC, Sartori R (2002) Influence of the layer charge and clay
particle size on the interactions between the cationic dye methylene blue and clays in an
aqueous suspension. J Colloid Interface Sci 255:254–259. https://doi.org/10.1006/jcis.2002.
8654
24. Okada T, Ide Y, Ogawa M (2012) Organic-inorganic hybrids based on ultrathin oxide layers:
designed nanostructures for molecular recognition. Chem Asian J 7:1980–1992. https://doi.
org/10.1002/asia.201101015
25. Okada T, Seki Y, Ogawa M (2014) Designed nanostructures of clay for controlled adsorption
of organic compounds. J Nanosci Nanotechnol 14:2121–2134. https://doi.org/10.1166/jnn.
2014.8597
26. Ruiz-Hitzky E, Aranda P, Akkari M, Khaorapapong N, Ogawa M (2019) Photoactive
nanoarchitectures based on clays incorporating TiO 2 and ZnO nanoparticles. Beilstein J
Nanotechnol 10:1140–1156. https://doi.org/10.3762/bjnano.10.114
27. Deepracha S, Vibulyaseak K, Ogawa M (2019) Complexation of TiO 2 with clays and clay
minerals for hierarchically designed functional hybrids. In: Advanced supramolecular
nanoarchitectonics. Elsevier, Amsterdam, pp 125–150
28. Intasa-ard SG, Ogawa M (2018) Layered silicates as a possible drug carrier. In: Tamanoi F
(ed) Mesoporous silica-based Nanomaterials and biomedical applications, part B. Elsevier,
Amsterdam, pp 117–136
29. Ogawa M (1998) Organized molecular assemblies on the surfaces of inorganic solidsphotofunctional inorganic-organic supramolecular systems. Annu Rep Prog Chem Sect C
Phys Chem 94:209. https://doi.org/10.1039/pc094209
30. Lagaly G, Ogawa M, Dékány I (2006) Chapter 7.3 clay mineral organic interactions. Dev Clay
Sci 1:309–377
31. Shichi T, Takagi K (2000) Clay minerals as photochemical reaction fields. J Photochem
Photobiol C: Photochem Rev 1:113–130. https://doi.org/10.1016/S1389-5567(00)00008-3
32. Granquist WT, Pollack SS (1960) A study of the synthesis of hectorite. Pergamon Press,
Oxford
33. Ogawa M, Wada T, Kuroda K (1995) Intercalation of pyrene into alkylammonium-exchanged
swelling layered silicates: the effects of the arrangements of the interlayer alkylammonium
ions on the states of adsorbates. Langmuir 11:4598–4600. https://doi.org/10.1021/
la00011a068
296
T. Yamaguchi et al.