process for the manufacture of highdensity polyethene using catalysts of
titanium(IV) chloride (TiCl 4 ) and aluminium alkyls (e.g. triethylaluminium, Al(C 2 H 5 ) 3 ). The process was
introduced in 1953 by the German
chemist Karl Ziegler (1898–1973). It
allowed the manufacture of polythene at lower temperatures (about
60°C) and pressures (about 1 atm.)
than used in the original process.
Moreover, the polyethene produced
had more straight-chain molecules,
giving the product more rigidity and
a higher melting point than the earlier low-density polyethene. The reaction involves the formation of a
titanium alkyl in which the titanium
can coordinate directly to the pi
bond in ethene.
In 1954 the process was developed
further by the Italian chemist Giulio
Natta (1903–79), who extended the
use of Ziegler’s catalysts (and similar
catalysts) to other alkenes. In particular he showed how to produce stereospeciÜc polymers of propene.
zinc Symbol Zn. A blue-white metallic element; a.n. 30; r.a.m. 65.38; r.d.
7.1; m.p. 419.88°C; b.p. 907°C. It occurs in sphalerite (or zinc blende,
ZnS), which is found associated with
the lead sulphide, and in smithsonite
(ZnCO 3 ). Ores are roasted to give the
oxide and this is reduced with carbon
(coke) at high temperature, the zinc
vapour being condensed. Alternatively, the oxide is dissolved in sulphuric acid and the zinc obtained by
electrolysis. There are Üve stable isotopes (mass numbers 64, 66, 67, 68,
and 70) and six radioactive isotopes
are known. The metal is used in galvanizing and in a number of alloys
(brass, bronze, etc.). Chemically it is a
reactive metal, combining with oxygen and other nonmetals and reacting with dilute acids to release
hydrogen. It also dissolves in alkalis
to give *zincates. Most of its compounds contain the Zn
2+ ion.
A
• Information from the WebElements site
zincate A salt formed in solution by
dissolving zinc or zinc oxide in alkali.
The formula is often written ZnO 2
2–
although in aqueous solution the
ions present are probably complex
ions in which the Zn
2+ is coordinated
to OH
– ions. ZnO 2
2– ions may exist in
molten sodium zincate, but most
solid ‘zincates’ are mixed oxides.
zinc blende A mineral form of
*zinc sulphide, ZnS, the principal ore
of zinc (see sphalerite).
zinc-blende structure See sphalerite structure.
zinc chloride A white crystalline
compound, ZnCl 2 . The anhydrous
salt, which is deliquescent, can be
made by the action of hydrogen chloride gas on hot zinc; r.d. 2.9; m.p.
283°C; b.p. 732°C. It has a relatively
low melting point and sublimes easily, indicating that it is a molecular
compound rather than ionic. Various
hydrates also exist. Zinc chloride is
used as a catalyst, dehydrating agent,
and Ûux for hard solder. It was once
known as butter of zinc.
zinc chloride cell See dry cell.
zinc group The group of elements
in the periodic table consisting of
zinc (Zn), cadmium (Cd), and mercury (Hg). See group 2 elements.
zincite A mineral form of *zinc
oxide, ZnO.
zinc oxide A powder, white when
cold and yellow when hot, ZnO; r.d.
5.606; m.p. 1975°C. It occurs naturally as a reddish orange ore zincite,
and can also be made by oxidizing
hot zinc in air. It is amphoteric,
forming *zincates with bases. It is
used as a pigment (Chinese white)
563
zinc oxide
z
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titanium(IV) chloride (TiCl 4 ) and aluminium alkyls (e.g. triethylaluminium, Al(C 2 H 5 ) 3 ). The process was
introduced in 1953 by the German
chemist Karl Ziegler (1898–1973). It
allowed the manufacture of polythene at lower temperatures (about
60°C) and pressures (about 1 atm.)
than used in the original process.
Moreover, the polyethene produced
had more straight-chain molecules,
giving the product more rigidity and
a higher melting point than the earlier low-density polyethene. The reaction involves the formation of a
titanium alkyl in which the titanium
can coordinate directly to the pi
bond in ethene.
In 1954 the process was developed
further by the Italian chemist Giulio
Natta (1903–79), who extended the
use of Ziegler’s catalysts (and similar
catalysts) to other alkenes. In particular he showed how to produce stereospeciÜc polymers of propene.
zinc Symbol Zn. A blue-white metallic element; a.n. 30; r.a.m. 65.38; r.d.
7.1; m.p. 419.88°C; b.p. 907°C. It occurs in sphalerite (or zinc blende,
ZnS), which is found associated with
the lead sulphide, and in smithsonite
(ZnCO 3 ). Ores are roasted to give the
oxide and this is reduced with carbon
(coke) at high temperature, the zinc
vapour being condensed. Alternatively, the oxide is dissolved in sulphuric acid and the zinc obtained by
electrolysis. There are Üve stable isotopes (mass numbers 64, 66, 67, 68,
and 70) and six radioactive isotopes
are known. The metal is used in galvanizing and in a number of alloys
(brass, bronze, etc.). Chemically it is a
reactive metal, combining with oxygen and other nonmetals and reacting with dilute acids to release
hydrogen. It also dissolves in alkalis
to give *zincates. Most of its compounds contain the Zn
2+ ion.
A
• Information from the WebElements site
zincate A salt formed in solution by
dissolving zinc or zinc oxide in alkali.
The formula is often written ZnO 2
2–
although in aqueous solution the
ions present are probably complex
ions in which the Zn
2+ is coordinated
to OH
– ions. ZnO 2
2– ions may exist in
molten sodium zincate, but most
solid ‘zincates’ are mixed oxides.
zinc blende A mineral form of
*zinc sulphide, ZnS, the principal ore
of zinc (see sphalerite).
zinc-blende structure See sphalerite structure.
zinc chloride A white crystalline
compound, ZnCl 2 . The anhydrous
salt, which is deliquescent, can be
made by the action of hydrogen chloride gas on hot zinc; r.d. 2.9; m.p.
283°C; b.p. 732°C. It has a relatively
low melting point and sublimes easily, indicating that it is a molecular
compound rather than ionic. Various
hydrates also exist. Zinc chloride is
used as a catalyst, dehydrating agent,
and Ûux for hard solder. It was once
known as butter of zinc.
zinc chloride cell See dry cell.
zinc group The group of elements
in the periodic table consisting of
zinc (Zn), cadmium (Cd), and mercury (Hg). See group 2 elements.
zincite A mineral form of *zinc
oxide, ZnO.
zinc oxide A powder, white when
cold and yellow when hot, ZnO; r.d.
5.606; m.p. 1975°C. It occurs naturally as a reddish orange ore zincite,
and can also be made by oxidizing
hot zinc in air. It is amphoteric,
forming *zincates with bases. It is
used as a pigment (Chinese white)
563
zinc oxide
z
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