CARBON-CARBON BOND FORMING REACTIONS
63
I.A.7.b.3-3 Curran, D.P. and Liu, H., JCS(Pl), 1377; Parsons, P.J. and
Caddick, S., T, 50, 13523.
'Ν'
,R
Bu,SnH PhOC
(CH 2 ) 4 CH=CHC0 2 Et
Et0 2 C
27-42%
other 1,5-H abstractions reported
I.A.7.b.3-4 Nishida, M., Nishida, A. et al., JACS, 116, 6455.
™ Me
M e ^ P h B u 3 S n H
BF 3 »OEt 2
PhH, 0°C
. .
M e
Me^pPh
O* >..
Me
Me
82%, 9:1 (R:S)
I.A.7.b.3-5 Dygutsch, D.P. et al., SL, 363.
CHC1 2 RBu 2 SnH
►
R
z
R = a polymer support
29-99%
63
I.A.7.b.3-3 Curran, D.P. and Liu, H., JCS(Pl), 1377; Parsons, P.J. and
Caddick, S., T, 50, 13523.
'Ν'
,R
Bu,SnH PhOC
(CH 2 ) 4 CH=CHC0 2 Et
Et0 2 C
27-42%
other 1,5-H abstractions reported
I.A.7.b.3-4 Nishida, M., Nishida, A. et al., JACS, 116, 6455.
™ Me
M e ^ P h B u 3 S n H
BF 3 »OEt 2
PhH, 0°C
. .
M e
Me^pPh
O* >..
Me
Me
82%, 9:1 (R:S)
I.A.7.b.3-5 Dygutsch, D.P. et al., SL, 363.
CHC1 2 RBu 2 SnH
►
R
z
R = a polymer support
29-99%