SYNTHESIS OF HETEROCYCLES
261
IV.F-33 Bosch, J. et al., JOC, 59, 10.
Cu
1. nBuLi
2. NBS
N /
3. tBuLi (2)
I
4 . E
+
H
5. TBAF
IV.F-34 Ishikura, M. and Terashima, M., JOC, 59, 2634; see also:
Labadie, S.S. and Teng, E., JOC, 59, 4250.
Co
1. tBuLi
BEt 3
2. CO
f
PdCl 2 (PPh 3 ) 2
*f
Me
RX
20-80%
M e
IV.F-35 Pinto, A.C. et al., TL, 35, 8923.
iO
BH 3 THF
IV.G. Pyridines. Quinolines. etc.
IV.G-1 Whitby, R.J. et al., SL, 451; see also: Kinoshita, A. and Mori,
M., SL, 1020.
2
ψ
T .
¥
α-Ό:
1. Cp 2 ZrBn
-78 °C
2.H 2 0
91%, 4:1
261
IV.F-33 Bosch, J. et al., JOC, 59, 10.
Cu
1. nBuLi
2. NBS
N /
3. tBuLi (2)
I
4 . E
+
H
5. TBAF
IV.F-34 Ishikura, M. and Terashima, M., JOC, 59, 2634; see also:
Labadie, S.S. and Teng, E., JOC, 59, 4250.
Co
1. tBuLi
BEt 3
2. CO
f
PdCl 2 (PPh 3 ) 2
*f
Me
RX
20-80%
M e
IV.F-35 Pinto, A.C. et al., TL, 35, 8923.
iO
BH 3 THF
IV.G. Pyridines. Quinolines. etc.
IV.G-1 Whitby, R.J. et al., SL, 451; see also: Kinoshita, A. and Mori,
M., SL, 1020.
2
ψ
T .
¥
α-Ό:
1. Cp 2 ZrBn
-78 °C
2.H 2 0
91%, 4:1