REDUCTIONS
ITT.G.2. N-O Cleavages
221
IILG.2-1 Dutta, B.K., Konwar, D., and Sandhu, J.S., JCR(S), 388.
R-N
O
NaSeH, EtOH, rt
R•N
O
80-94 %
IILG.2-2 Simpson, G.W. et al., CC, 2035.
O
Ar
N
/
Baker's Yeast
?
O
Ar
A X
X = O, CH 2
NH
OH
75%
III.G.3. Other Reductive Cleavages
III.G.3-1 Martens, J. et al., SC, 24, 1381.
R
H 2 N^
> N C0 2 H
cyclohexenone, 170°C
R
k C0 2 H
72-82 %
ITT.G.2. N-O Cleavages
221
IILG.2-1 Dutta, B.K., Konwar, D., and Sandhu, J.S., JCR(S), 388.
R-N
O
NaSeH, EtOH, rt
R•N
O
80-94 %
IILG.2-2 Simpson, G.W. et al., CC, 2035.
O
Ar
N
/
Baker's Yeast
?
O
Ar
A X
X = O, CH 2
NH
OH
75%
III.G.3. Other Reductive Cleavages
III.G.3-1 Martens, J. et al., SC, 24, 1381.
R
H 2 N^
> N C0 2 H
cyclohexenone, 170°C
R
k C0 2 H
72-82 %