REDUCTIONS
HI.F. Hetero Bond Reductions
213
III.F.l. C-O -> C-H
III.F.1-1 Oba, M. and Nishiyama, K., T, 50, 10193 and S, 624.
R-OH
PhNCS
NaH * RO
X
Ph TMS 3 SiH
•
N
AIRN
K _ M
I
H
82-99 %
III.F.1-2 Wustrow, DJ. et al., TL, 35, 61; see also: Saa, J.M. et al., JOC,
57, 5093.
Ph
Ph
HO
Et 3 SiH, L1CIO4, Et 2 0, rt
92%
III.F.1-3 Ollivier, J. and Salaün, J., SL, 949; Hayashi, T. et al., S, 526 and
JACS, 116, 775.
r ^ / ^
8 " *
3
Pd(0),THF,rt ,
[ > = ,
C . D
O n \ ) A c
HC0 2 Na or BuZnCl <>n
\ ^ S i R 3
77-90 %
HI.F. Hetero Bond Reductions
213
III.F.l. C-O -> C-H
III.F.1-1 Oba, M. and Nishiyama, K., T, 50, 10193 and S, 624.
R-OH
PhNCS
NaH * RO
X
Ph TMS 3 SiH
•
N
AIRN
K _ M
I
H
82-99 %
III.F.1-2 Wustrow, DJ. et al., TL, 35, 61; see also: Saa, J.M. et al., JOC,
57, 5093.
Ph
Ph
HO
Et 3 SiH, L1CIO4, Et 2 0, rt
92%
III.F.1-3 Ollivier, J. and Salaün, J., SL, 949; Hayashi, T. et al., S, 526 and
JACS, 116, 775.
r ^ / ^
8 " *
3
Pd(0),THF,rt ,
[ > = ,
C . D
O n \ ) A c
HC0 2 Na or BuZnCl <>n
\ ^ S i R 3
77-90 %