OXIDATIONS
189
II.F.2-5 Sharpless, K.B. et al., TL, 35, 5129.
Asymmetric Dihydroxylation of Olefins Containing Sulfur:
Chemoselective Oxidation of C-C Double bonds in the Presence of
Sulfides, 1,3-Dithianes, and Disulfides.
II.F.2-6 Boyd, D.R., Dalton, H. et al., JACS, 116, 1147.
P. putida
ör
E. coli
OH
OH
80 to 98 % e.e.
II.F.2-7 Cirillo, P.F. and Panek, J.S., JOC, 59, 3055; Krysan, DJ. et al.,
TA, 5, 625.
R 5 Si
OH
OH
R E
OSQ 4 ,
R
&
TMNO*
45-94 %
anti/syn = 1.4:1 to 147:1
II.F.3 Other Oxidative Additions to C-C Multiple Bonds
II.F.3-1 Shono, T., Kashimura, S. et al., 5, 895.
l:LiNQ 3 , e~ ^
OH
R ^ ^ R ·
2: NaSH, H 2 0
R
'R'
52-78 %