CARBON-CARBON BOND FORMING REACTIONS
7
LA.2-6 Davies, S.G. and Walters, I.A.S., JCS(Pl), 1129, 1141, 1411.
1) D U ^ N T ^
„ L A X /
1
-
l
> PIT
N ;
ph"
R ^
5
^ OR'
*, , - - ,
2)R"X
R
£
O R
'
R"
42-79%
1:1 to 13:1 anti
I.A.2-7 Ghelfi, F. et al., TL, 35, 7263.
Ch
C0 2 Me
« η # ¥ . Λ „
Cl
C0 2 Me
Y
z
CuBr/LiOMe
\ /
D
1
MeOH
C /\o 2 Me
17-81%
I.A.2-8 Quirion, J.-C. et al., TL, 35, 7223, 7227.
Ph
Ph
ΓΛ
x>
SBuLi
,
ΓΛ x>
H O
R
/ N
^ f
R"X,THF
H
°
R
^
^ R *
.„>*^R*
27-84%, 80-99% de
7
LA.2-6 Davies, S.G. and Walters, I.A.S., JCS(Pl), 1129, 1141, 1411.
1) D U ^ N T ^
„ L A X /
1
-
l
> PIT
N ;
ph"
R ^
5
^ OR'
*, , - - ,
2)R"X
R
£
O R
'
R"
42-79%
1:1 to 13:1 anti
I.A.2-7 Ghelfi, F. et al., TL, 35, 7263.
Ch
C0 2 Me
« η # ¥ . Λ „
Cl
C0 2 Me
Y
z
CuBr/LiOMe
\ /
D
1
MeOH
C /\o 2 Me
17-81%
I.A.2-8 Quirion, J.-C. et al., TL, 35, 7223, 7227.
Ph
Ph
ΓΛ
x>
SBuLi
,
ΓΛ x>
H O
R
/ N
^ f
R"X,THF
H
°
R
^
^ R *
.„>*^R*
27-84%, 80-99% de