OXIDATIONS
185
II.E-4 Morimoto, T. et al., BCJ, 67, 1492; Bhalerao, U.T. and Sridhar, M.,
7X,35, 1413.
O
s
NaBr02,CH 2 Cl 2
J
R
R' ~7+—:
: — . . „ »
„ - " ^
H - exchanged zeolite F-9
R
R'
50-87 %
II.E-5 Rozen, S. and Bareket, Y., CC, 1959.
^Â
\ ^ .
F 2 ,H 2 0,MeCN
J
V
o*N)
27-95 %
II.F. Oxidative Additions to C-C Multiple Bonds
II.F.l Epoxidations
II.F.1-1 Adam, W. and Richter, M.J., JOC, 59, 3341 ; Lassila, K.R. et al.
TL, 35, 8077; Shapovalov, V.V. and Poluektov, V.A., JOU, 30, 329.
R
^J^
„ . . , „ „ .
R'Me 2 Si
Λ
SiMe2R' „ Λ
.._ x
_
\ .^Q
10 2 , Ti(0*Pr) 4
R
\ζί
Me
I
OH
56-70 %
dr: 93:7 to 97:3
185
II.E-4 Morimoto, T. et al., BCJ, 67, 1492; Bhalerao, U.T. and Sridhar, M.,
7X,35, 1413.
O
s
NaBr02,CH 2 Cl 2
J
R
R' ~7+—:
: — . . „ »
„ - " ^
H - exchanged zeolite F-9
R
R'
50-87 %
II.E-5 Rozen, S. and Bareket, Y., CC, 1959.
^Â
\ ^ .
F 2 ,H 2 0,MeCN
J
V
o*N)
27-95 %
II.F. Oxidative Additions to C-C Multiple Bonds
II.F.l Epoxidations
II.F.1-1 Adam, W. and Richter, M.J., JOC, 59, 3341 ; Lassila, K.R. et al.
TL, 35, 8077; Shapovalov, V.V. and Poluektov, V.A., JOU, 30, 329.
R
^J^
„ . . , „ „ .
R'Me 2 Si
Λ
SiMe2R' „ Λ
.._ x
_
\ .^Q
10 2 , Ti(0*Pr) 4
R
\ζί
Me
I
OH
56-70 %
dr: 93:7 to 97:3