OXIDATIONS
175
ILA.1-8 Li, L. et al., JMC, 37, 2655; Yavari, I. and Shaabani, A., JCR(S),
274.
ÇH
O
Bno
% Â ^
O H
Bn
\ .A^
oH
1 I
«Bu 2 SnO
1 |
O
Ar
O
Ar
83%
ILA.1-9 Warner, P. et al., JMC, 37, 3090.
R ^ N
/ >
/ C F 3
EDC >CI2CHCO2H
Rs > \ ^ C F 3
|
|
DMSO, Ph-Me **
|
H
OH
H O
31-80%
ILA .2 Alcohols.Aldehvdes —> Acids. Esters
ILA.2-1 Firouzabadi, H. and Mohammadpoor-Baltork, I., SC, 24, 1065.
^ \
AgBr0 3
X 0 2 H
AK
OTMS
— * , »
A r
A I C I 3
8 2.95 %
Use of NaBK>3 affords the aldehyde
II.A.2-2 Babu, B.R. and Balasubramaniam, K.K., OPP, 26, 123
R-CHO
Ν ! ? ? Λ >
RC0 2 H
aq MeCN
^
%
175
ILA.1-8 Li, L. et al., JMC, 37, 2655; Yavari, I. and Shaabani, A., JCR(S),
274.
ÇH
O
Bno
% Â ^
O H
Bn
\ .A^
oH
1 I
«Bu 2 SnO
1 |
O
Ar
O
Ar
83%
ILA.1-9 Warner, P. et al., JMC, 37, 3090.
R ^ N
/ >
/ C F 3
EDC >CI2CHCO2H
Rs > \ ^ C F 3
|
|
DMSO, Ph-Me **
|
H
OH
H O
31-80%
ILA .2 Alcohols.Aldehvdes —> Acids. Esters
ILA.2-1 Firouzabadi, H. and Mohammadpoor-Baltork, I., SC, 24, 1065.
^ \
AgBr0 3
X 0 2 H
AK
OTMS
— * , »
A r
A I C I 3
8 2.95 %
Use of NaBK>3 affords the aldehyde
II.A.2-2 Babu, B.R. and Balasubramaniam, K.K., OPP, 26, 123
R-CHO
Ν ! ? ? Λ >
RC0 2 H
aq MeCN
^
%