CARBON-CARBON BOND FORMING REACTIONS
I.G.3-6 Negishi, E. et al., JACS, 116, 8404.
1. Et 2 AICl, Ti(0'Pr) 4
hexane, 22°C, 24h
155
Et
k /^.
20
2>
\^%
2h
OH
88%
eis = >95%
I.G.3-7 Takacs, J.M. and Lawson, E.C., OM, 13, 4787.
Et0 2 C^^^^ RhC , 3> pph3 ^EtQ 2 C^Y^^X
Et0 2 C
/ V-^ v ^% t HNRR
1 , TFE * E t0 2 C
/ V^\^^
NRR
1
46-81%
cis:trans = 1-8:1
I.G.3-8 Agrios, K.A. and Srebnik, M., JOC, 59, 5468.
R
R
R^k ZnEt
+ X.
R
1
DMF, rt
*► R^^^^^x^R
1
I.G.3-9 Moeller, K.D. et al., JOC, 59, 2381.
OMe
Pt anode
19-98%
OMe
OMe L1CIO4, THF/MeOH
Me
I.G.3-6 Negishi, E. et al., JACS, 116, 8404.
1. Et 2 AICl, Ti(0'Pr) 4
hexane, 22°C, 24h
155
Et
k /^.
20
2>
\^%
2h
OH
88%
eis = >95%
I.G.3-7 Takacs, J.M. and Lawson, E.C., OM, 13, 4787.
Et0 2 C^^^^ RhC , 3> pph3 ^EtQ 2 C^Y^^X
Et0 2 C
/ V-^ v ^% t HNRR
1 , TFE * E t0 2 C
/ V^\^^
NRR
1
46-81%
cis:trans = 1-8:1
I.G.3-8 Agrios, K.A. and Srebnik, M., JOC, 59, 5468.
R
R
R^k ZnEt
+ X.
R
1
DMF, rt
*► R^^^^^x^R
1
I.G.3-9 Moeller, K.D. et al., JOC, 59, 2381.
OMe
Pt anode
19-98%
OMe
OMe L1CIO4, THF/MeOH
Me