CARBON-CARBON BOND FORMING REACTIONS
I.G.2-22 Ryu, I., Sonoda, N. et al., SL, 1009.
153
R
CO, LTA, Ph-H
OH
-
-
►
R
OAc
57-62%
I.G.3. Other Synthesis via Organometallics
I.G.3-1 Chamberlin, S. and Wulff, W.D., JOC, 59, 3047; Chan, K.S.
and Mak, C.C, T, 50, 2003; de Meijere, A. et al., CC, 1679; see also:
Ikegami, S. et al., SC, 24, 3277.
OMe
R.
(CO) 5 Cr
1. THF, 45-60°C
2. CAN
*
TBDMS
R s
I.G.3-2 Hong, C.Y. and Overman, L.E., TL, 35, 3453.
Me0 2 CN,
H
Pd(Q 2 CCF 3 ) 2 (PPh 3 ) 2
R 3 N, Ph-Me, Δ
*
Μ Ρ Ο , , Γ Ν
OMe
OH
56%
I.G.2-22 Ryu, I., Sonoda, N. et al., SL, 1009.
153
R
CO, LTA, Ph-H
OH
-
-
►
R
OAc
57-62%
I.G.3. Other Synthesis via Organometallics
I.G.3-1 Chamberlin, S. and Wulff, W.D., JOC, 59, 3047; Chan, K.S.
and Mak, C.C, T, 50, 2003; de Meijere, A. et al., CC, 1679; see also:
Ikegami, S. et al., SC, 24, 3277.
OMe
R.
(CO) 5 Cr
1. THF, 45-60°C
2. CAN
*
TBDMS
R s
I.G.3-2 Hong, C.Y. and Overman, L.E., TL, 35, 3453.
Me0 2 CN,
H
Pd(Q 2 CCF 3 ) 2 (PPh 3 ) 2
R 3 N, Ph-Me, Δ
*
Μ Ρ Ο , , Γ Ν
OMe
OH
56%