CARBON-CARBON BOND FORMING REACTIONS
151
I.G.2-12 Hu, Y. et al., SC, 24, 1743.
, Γ Η Ϊ ι Γ η
Co(PPh 3 ) 2 Cl 2 , PTC, aq NaOH
ArCH 2 X + CO
► ArCH 2 C0 2 H
<88%
I.G.2-13 Piotti, M.E. and Alper, H., JOC, 59, 1956.
R
1
R
■ O H
R*
trans-[Cy 3 P) 2 Pd(H)(H 2 0)]
+ BF 4 -
CO, PTSA, THF
R
C0 2 H
43-74%
I.G.2-14 Botteghi, C. et al., JOC, 59, 7125.
X
X v
^
CO, H 2 , HRh(CO)(PPh 3 ) 3
ff
\
Ph-H, 80°C, 24h
Me 2 N
OHC
I.G.2-15 Khumtaveeporn, K. and Alper, H., JOC, 59, 1414; Mitsudo,
T., Watanabe, Y. et al., JOC, 59, 7759; Miyazawa, M. and Yamamoto, K.,
CL, 491.
O
,
CO, [RH(COD)CI] 2
II
,
PhCFbSCHîNRR
1
—
*
.
2
»
PhCHXSCH^RR
1
2
2
Ph-Me, 140°C
2
2
68-92%
I.G.2-16 Brunet, J.J., Neibecker, D. et al., SC, 24, 2827; see also:
Brookhart, M. et al., JACS, 116, 1869.
C, 2 H 25 Br + EtI
K 2
F e (
c o > 4 f c
c 12 H 2s COEt
90%
151
I.G.2-12 Hu, Y. et al., SC, 24, 1743.
, Γ Η Ϊ ι Γ η
Co(PPh 3 ) 2 Cl 2 , PTC, aq NaOH
ArCH 2 X + CO
► ArCH 2 C0 2 H
<88%
I.G.2-13 Piotti, M.E. and Alper, H., JOC, 59, 1956.
R
1
R
■ O H
R*
trans-[Cy 3 P) 2 Pd(H)(H 2 0)]
+ BF 4 -
CO, PTSA, THF
R
C0 2 H
43-74%
I.G.2-14 Botteghi, C. et al., JOC, 59, 7125.
X
X v
^
CO, H 2 , HRh(CO)(PPh 3 ) 3
ff
\
Ph-H, 80°C, 24h
Me 2 N
OHC
I.G.2-15 Khumtaveeporn, K. and Alper, H., JOC, 59, 1414; Mitsudo,
T., Watanabe, Y. et al., JOC, 59, 7759; Miyazawa, M. and Yamamoto, K.,
CL, 491.
O
,
CO, [RH(COD)CI] 2
II
,
PhCFbSCHîNRR
1
—
*
.
2
»
PhCHXSCH^RR
1
2
2
Ph-Me, 140°C
2
2
68-92%
I.G.2-16 Brunet, J.J., Neibecker, D. et al., SC, 24, 2827; see also:
Brookhart, M. et al., JACS, 116, 1869.
C, 2 H 25 Br + EtI
K 2
F e (
c o > 4 f c
c 12 H 2s COEt
90%