CARBON-CARBON BOND FORMING REACTIONS
LG.2-4 Pearson, A.J. et al., OM, 13, 578, 1656.
149
TMS
TMS
(0.
CO, Fe(CO) 5
Ph-Me, 125-130°C, 24h
: =
TMS
R
R
TMS
25-85%
I.G.2-5 Chung, Y.K. et al., JACS, 116, 8793, 2163.
R
1
CO, catalyst, DME, 100°C
«
0»
R
I.G.2-6 Buchwald, S.L. et al., JACS, 116, 8593.
53-97%
R
r
R
V
R
x
3 SiCN, Cp 2 Ti(PMe 3 ) 2
45°C, 18-24h
*- yC\\=Q
42-80%
I.G.2-7 Ojima, I. et al., JOC, 59, 7594.
^ _ _ _
CO, 'BuMejSiH
E t 0 2 C . /
= = =
Rh(acac)(CO) 2 EtQ 2 C
EtO^cA
_
Ph-Me, 50°C
£ t 0 c
TBDMS
O
90%
LG.2-4 Pearson, A.J. et al., OM, 13, 578, 1656.
149
TMS
TMS
(0.
CO, Fe(CO) 5
Ph-Me, 125-130°C, 24h
: =
TMS
R
R
TMS
25-85%
I.G.2-5 Chung, Y.K. et al., JACS, 116, 8793, 2163.
R
1
CO, catalyst, DME, 100°C
«
0»
R
I.G.2-6 Buchwald, S.L. et al., JACS, 116, 8593.
53-97%
R
r
R
V
R
x
3 SiCN, Cp 2 Ti(PMe 3 ) 2
45°C, 18-24h
*- yC\\=Q
42-80%
I.G.2-7 Ojima, I. et al., JOC, 59, 7594.
^ _ _ _
CO, 'BuMejSiH
E t 0 2 C . /
= = =
Rh(acac)(CO) 2 EtQ 2 C
EtO^cA
_
Ph-Me, 50°C
£ t 0 c
TBDMS
O
90%