CARBON-CARBON BOND FORMING REACTIONS
143
I.F.3-19 Knöchel, P., Cahiez, G. et al., TL, 35, 1177; Jackson, R.F.W.
et al., SL, 379; Rossi, R. et al., TL, 35, 6913.
RCH 2 ZnBr + Ari
THF, Pd(dppf)CI 2
RCH 2 -Ar
69-75%
I.F.3-20 Achiwa, K. et al., SL, 291; Dashkina, L.R. et al., JOU, 30,
422; Song, Z.Z. and Wong, H.N.C., LA, 29.
ÌI +PhOTf
P d ( O A c ) * c
h i r a' phosphine^
"
R 3 N, HC0 2 H, DMSO
60-94%
e.e. = 5-71%
I.F.3-21 Lewis, S.B. and Borden, W.T., TL, 35, 1357; Wulff, W.D. et
al., JACS, 116, 7616; Zora, M. and Herndon, J.W., OM, 13, 3370.
of
Ph
Ph
+ PhHgCF 3
Nal, Ph-H, reflux
I.F.3-22 Coe, J.W. et al., TL, 35, 6627.
77%
Base