CARBON-CARBON BOND FORMING REACTIONS
I.E.3-25 Nair, H.K. and Burton, D.J., JACS, 116, 6041.
O
II
(RO) 3 P + BrCF 2 CF 2 I
2 3 g h »
(RO) 3 PCF 2 CF 2 I
42-48%
129
I.E.3-26 Garrido, N.M. et al., Γ, 50, 10995; Nuss, J.M. and Murphy,
M.M., TL, 35, 37.
C0 2 Me
hv
86%
I.E.3-27 Piva, O., SL, 729.
C0 2 Me
R
]
C0 2 Et
h v
R . . R
R
EtNH, CH 2 CI 2
C0 2 Et
F
52-81%
E:Z = 2:1
I.E.3-25 Nair, H.K. and Burton, D.J., JACS, 116, 6041.
O
II
(RO) 3 P + BrCF 2 CF 2 I
2 3 g h »
(RO) 3 PCF 2 CF 2 I
42-48%
129
I.E.3-26 Garrido, N.M. et al., Γ, 50, 10995; Nuss, J.M. and Murphy,
M.M., TL, 35, 37.
C0 2 Me
hv
86%
I.E.3-27 Piva, O., SL, 729.
C0 2 Me
R
]
C0 2 Et
h v
R . . R
R
EtNH, CH 2 CI 2
C0 2 Et
F
52-81%
E:Z = 2:1