CARBON-CARBON BOND FORMING REACTIONS
105
I.E.1-11 Hickey, E.R. and Paquette, L.A., TL, 35, 2309; see also:
Hudlicky, T. and McKibben, B.P., JCS(Pl), 485.
OTf
a
CsF, DMSO
TMS
74%
I.E.1-12 Roush, W.R. and Sciotti, R.J., JACS, 116, 6457.
,0TB DPS
^OTBDPS
O. . O
1 >-'Bu
Y
o^o
Ph-Me
Me 120°C, 20h
TMS OMOM
I.E.1-13 Posner, G.H. et al., 7L, 35, 1321.
ςχΛ
SiO,
CH 2 CI 2 , 25°C
OBu
C0 2 Me
No reaction occurs without Si0 2
TMS OMOM
40-45%
OBu
105
I.E.1-11 Hickey, E.R. and Paquette, L.A., TL, 35, 2309; see also:
Hudlicky, T. and McKibben, B.P., JCS(Pl), 485.
OTf
a
CsF, DMSO
TMS
74%
I.E.1-12 Roush, W.R. and Sciotti, R.J., JACS, 116, 6457.
,0TB DPS
^OTBDPS
O. . O
1 >-'Bu
Y
o^o
Ph-Me
Me 120°C, 20h
TMS OMOM
I.E.1-13 Posner, G.H. et al., 7L, 35, 1321.
ςχΛ
SiO,
CH 2 CI 2 , 25°C
OBu
C0 2 Me
No reaction occurs without Si0 2
TMS OMOM
40-45%
OBu