GLOSSARY
XVII
Fmoc 9-fluorenylmethoxycarbonyl
fod
2,2-dimethyl-3,5-octanedione
Fs = flosyl fluorosulfonate
FTT 1 -fluoro-2,4,6-trimethylpyridinium inflate
FVP flash vapor pyrolysis
Gr
graphite
h
hours
Hap hydroxyapatite
Hbz 2-hydroxybenzyl
hfacac hexafluoroacetylacetone
HFB heptafluorobutyl ether
HFIP l,l,l,3,3,3-hexafluoro-2propanol
HGK 4-hydroxy-2-ketoglutarate
Hmb 2-hydroxy-4-methoxybenzyl
HMDS 1,1,1,3,3,3hexamethyldisilazane
HMPA = HMPT hexamethylphosphoramide
hv
irradiation with light
HTIB [hydroxy(p-tolylsulfonyloxy)iodo] benzene
L-selectride" lithium tri^butylborohydride
L.R. Lawesson's reagent
LAH lithium aluminum hydride
LDA lithium diisopropylamide
LDBB lithium 4,4'i
butylbiphenylide
liq.
liquid
LTMP lithium 2,2,6,6-tetramethylpiperidide
bromo-2,6-dir
butylphenoxide)
dir
butyl-4-methylphenoxide)
MAPH methylaluminumbis(2,6diphenoxide)
MBT 2-mercaptobenzothiazole
MCPBA m-chloroperbenzoic acid
Me
methyl
Mek methyl ethyl ketone
MEM ß-methoxyethoxymethyl
Mes = mesityl 2,4,6-trimethylphenyl
MMPP magnesium monoperoxyphthalate
MOM methoxymethyl
MPD 1 -methylpyrrolidone
MPM methoxy(phenylthio)methyl
Mpm = PMB p-methoxy-benzyl
MS molecular sieves
Ms
methanesulfonyl
MSA methanesulfonic acid
MSH o-mesitylenesulfonyl
hydroxylamine
MTO methyltrioxorhenium
MTPA methoxy-a-trifluoromethylphenylacetyl
MV
2
+ methyl viologen
mw microwave
Naph = Np naphthyl
NBS N-bromosuccinimide
NCS N-chlorosuccinimide
NFOBS N-fluoro-O-benzenedisulfonimide
NIS N-iodosuccinimide
NMO ^V-methylmorpholine-iVoxide
Np = Naph naphthyl
NPM N-phenylmaleimide
NR
no reaction
Nuc general nucleophile
[O]
general oxidation
PBP pyridinium bromide
perbromide
PCC pyridinium chlorochromate
PDC pyridinium dichromate
PEG polyethylene glycol